2-¹³C-glycolic acid

Base Information

• Chemical Name: 2-¹³C-glycolic acid
• CAS No.: 81277-97-6
• Molecular Formula: C₂H₄O₃
• Molecular Weight: 77.041
• Mol file: 81277-97-6.mol

Synonyms:2-¹³C-glycolic acid

Chemical Property of 2-¹³C-glycolic acid

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 2-¹³C-glycolic acid

There total 3 articles about 2-¹³C-glycolic acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

1,3-13C2-glycerol (102088-01-7) → formic acid (64-18-6) + (13C)-formic acid (1633-56-3) + 2-13C-glycolic acid (81277-97-6)

Guidance literature:

With C₁₃H₁₆ClN₃O₂Pd; dihydrogen peroxide; at 60 ℃; for 6h;

DOI:10.1016/j.tetlet.2013.06.041

Reference yield:

(2-13C)acetic acid (1563-80-0) → methanol (67-56-1) + formic acid (64-18-6) + (13C)-formic acid (1633-56-3) + (13C)-hydroxymethyl hydroperoxide + (13C)-methyl hydroperoxide + 2-13C-glycolic acid (81277-97-6) + (13)CH4O2

Guidance literature:

With dihydrogen peroxide; In water; at 50 ℃;

DOI:10.1021/ja403060n

Reference yield:

6-13C-D-glucose (70491-70-2,478518-62-6) → C2(13)CH6O4 (1185549-51-2) + C3(13)CH8O5 (1185549-49-8) + oxalic acid (144-62-7,97993-78-7) + 2-13C-glycolic acid (81277-97-6)

Guidance literature:

With sodium hydroxide; sulfuric acid; ozone; In water; at 20 ℃; pH=2.5;

DOI:10.1016/j.carres.2009.05.012

upstream raw materials:

6-¹³C-D-glucose

1,3-¹³C₂-glycerol

(2-¹³C)acetic acid