benzyl 2-methylthio-2-[5-[1-(2-ethoxycarbonyl)butenyl]-2-methoxyphenyl]acetate

Base Information

Chemical Name:benzyl 2-methylthio-2-[5-[1-(2-ethoxycarbonyl)butenyl]-2-methoxyphenyl]acetate
CAS No.:378231-94-8
Molecular Formula:C₂₄H₂₈O₅S
Molecular Weight:428.549
Hs Code.:

Synonyms:benzyl 2-methylthio-2-[5-[1-(2-ethoxycarbonyl)butenyl]-2-methoxyphenyl]acetate

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Chemical Property of benzyl 2-methylthio-2-[5-[1-(2-ethoxycarbonyl)butenyl]-2-methoxyphenyl]acetate

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Technology Process of benzyl 2-methylthio-2-[5-[1-(2-ethoxycarbonyl)butenyl]-2-methoxyphenyl]acetate

There total 4 articles about benzyl 2-methylthio-2-[5-[1-(2-ethoxycarbonyl)butenyl]-2-methoxyphenyl]acetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 100-39-0
benzyl bromide

: 378231-94-8
benzyl 2-methylthio-2-[5-[1-(2-ethoxycarbonyl)butenyl]-2-methoxyphenyl]acetate

Guidance literature:: Multi-step reaction with 2 steps

1.1: 76 percent / K₂CO₃ / dimethylformamide / 5 h / 20 °C

2.1: NaH / tetrahydrofuran / 1 h

2.2: tetrahydrofuran / 4 h / 0 - 20 °C

With sodium hydride; potassium carbonate; In tetrahydrofuran; N,N-dimethyl-formamide;
DOI:10.1021/jm0205144

Reference yield:

: 123-11-5
4-methoxy-benzaldehyde

: 378231-94-8
benzyl 2-methylthio-2-[5-[1-(2-ethoxycarbonyl)butenyl]-2-methoxyphenyl]acetate

Guidance literature:: Multi-step reaction with 4 steps

1.1: TiCl₃ / CH₂Cl₂ / 0.25 h / 20 °C

1.2: 52 percent / CH₂Cl₂; CCl₄ / 24 h / Heating

2.1: aq. NaOH / ethanol / 3 h / 20 °C

3.1: 76 percent / K₂CO₃ / dimethylformamide / 5 h / 20 °C

4.1: NaH / tetrahydrofuran / 1 h

4.2: tetrahydrofuran / 4 h / 0 - 20 °C

With sodium hydroxide; titanium(III) chloride; sodium hydride; potassium carbonate; In tetrahydrofuran; ethanol; dichloromethane; N,N-dimethyl-formamide;
DOI:10.1021/jm0205144

Reference yield:

: 378232-46-3
2-methylthio-2-(5-formyl-2-methoxyphenyl)acetic acid

: 378231-94-8
benzyl 2-methylthio-2-[5-[1-(2-ethoxycarbonyl)butenyl]-2-methoxyphenyl]acetate

Guidance literature:: Multi-step reaction with 2 steps

1.1: 76 percent / K₂CO₃ / dimethylformamide / 5 h / 20 °C

2.1: NaH / tetrahydrofuran / 1 h

2.2: tetrahydrofuran / 4 h / 0 - 20 °C

With sodium hydride; potassium carbonate; In tetrahydrofuran; N,N-dimethyl-formamide;
DOI:10.1021/jm0205144