potassium (5,10,15,20-tetrakis(p-tolyl)porphyrinato)iridate(I)

Base Information

• Chemical Name: potassium (5,10,15,20-tetrakis(p-tolyl)porphyrinato)iridate(I)
• CAS No.: 1215770-07-2
• Molecular Formula: C₄₈H₃₆IrN₄*K
• Molecular Weight: 900.159
• Mol file: 1215770-07-2.mol

Synonyms:potassium (5,10,15,20-tetrakis(p-tolyl)porphyrinato)iridate(I)

Chemical Property of potassium (5,10,15,20-tetrakis(p-tolyl)porphyrinato)iridate(I)

Chemical Property:

Purity/Quality:

Safty Information:

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• Hazard Codes: 

MSDS Files:

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Technology Process of potassium (5,10,15,20-tetrakis(p-tolyl)porphyrinato)iridate(I)

There total 8 articles about potassium (5,10,15,20-tetrakis(p-tolyl)porphyrinato)iridate(I) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

(5,10,15,20-tetrakis(p-tolyl)porphyrinato)carbonyliridium(III) chloride (872415-81-1) → (hydrido)(5,10,15,20-tetrakis(p-tolyl)porphyrinato)iridium(III) (105139-33-1) + potassium (5,10,15,20-tetrakis(p-tolyl)porphyrinato)iridate(I) (1215770-07-2)

Guidance literature:

With water; potassium hydroxide; In benzene-d6; at 120 ℃; for 5h; Darkness;

DOI:10.1021/om200251k

Reference yield: 71.0%

bromo(carbonyl)(5,10,15,20-tetrakis(p-tolyl)porphyrinato)iridium(III) (1280227-67-9) → (hydrido)(5,10,15,20-tetrakis(p-tolyl)porphyrinato)iridium(III) (105139-33-1) + potassium (5,10,15,20-tetrakis(p-tolyl)porphyrinato)iridate(I) (1215770-07-2)

Guidance literature:

With water; potassium hydroxide; In benzene-d6; at 120 ℃; for 5h; Darkness;

DOI:10.1021/om200251k

Reference yield:

[Ir(5,10,15,20-tetra-p-tolylporphyrinato dianion)(SiEt3)] (1043600-78-7) + potassium hydroxide → hexaethyl disiloxane (994-49-0) + potassium (5,10,15,20-tetrakis(p-tolyl)porphyrinato)iridate(I) (1215770-07-2) + potassium triethylsilanolate (25706-33-6)

Guidance literature:

In benzene-d6; at 200 ℃; for 120h; Time; Inert atmosphere;

DOI:10.1021/om301196t

upstream raw materials:

(hydrido)(5,10,15,20-tetrakis(p-tolyl)porphyrinato)iridium(III)

(5,10,15,20-tetrakis(p-tolyl)porphyrinato)carbonyliridium(III) chloride

bromo(carbonyl)(5,10,15,20-tetrakis(p-tolyl)porphyrinato)iridium(III)

iodo(carbonyl)(5,10,15,20-tetrakis(p-tolyl)porphyrinato)iridium(III)