bromo(carbonyl)(5,10,15,20-tetrakis(p-tolyl)porphyrinato)iridium(III)

Base Information

Chemical Name:bromo(carbonyl)(5,10,15,20-tetrakis(p-tolyl)porphyrinato)iridium(III)
CAS No.:1280227-67-9
Molecular Formula:C₄₉H₃₆BrIrN₄O
Molecular Weight:968.975
Hs Code.:

Synonyms:bromo(carbonyl)(5,10,15,20-tetrakis(p-tolyl)porphyrinato)iridium(III)

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Chemical Property of bromo(carbonyl)(5,10,15,20-tetrakis(p-tolyl)porphyrinato)iridium(III)

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Technology Process of bromo(carbonyl)(5,10,15,20-tetrakis(p-tolyl)porphyrinato)iridium(III)

There total 5 articles about bromo(carbonyl)(5,10,15,20-tetrakis(p-tolyl)porphyrinato)iridium(III) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 62.0%

: 872415-81-1
(5,10,15,20-tetrakis(p-tolyl)porphyrinato)carbonyliridium(III) chloride

: 1280227-67-9
bromo(carbonyl)(5,10,15,20-tetrakis(p-tolyl)porphyrinato)iridium(III)

Guidance literature:: With bromobenzene; at 200 ℃; for 48h; Inert atmosphere; Darkness; Neat (no solvent);
DOI:10.1021/om200251k

Reference yield: 62.0%

: 108-86-1,52753-63-6
bromobenzene

: 872415-81-1
(5,10,15,20-tetrakis(p-tolyl)porphyrinato)carbonyliridium(III) chloride

: 1224699-27-7
phenyl(5,10,15,20-tetrakis(p-tolyl)porphyrinato)iridium(III)

: 1280227-67-9
bromo(carbonyl)(5,10,15,20-tetrakis(p-tolyl)porphyrinato)iridium(III)

Guidance literature:: In neat (no solvent); Ir-complex and C6H5Br were heated in a Teflon-screw-capped tube at 200°C under N2 for 2 days;
DOI:10.1021/om200251k

Reference yield: 54.0%

: 872415-81-1
(5,10,15,20-tetrakis(p-tolyl)porphyrinato)carbonyliridium(III) chloride

: 1643-19-2
tetrabutylammomium bromide

: 1280227-67-9
bromo(carbonyl)(5,10,15,20-tetrakis(p-tolyl)porphyrinato)iridium(III)

Guidance literature:: With AgBF₄; In dichloromethane; according to Song X., Chan K. S., Organometallics, 2007, 26, 965; (N2); mixt. of Ir complex and Ag salt in CH2Cl2 in wrapped foil was stirred atambient temp. for 2 d; filtered; Bu4NBr (5-10 equiv.) was added; stirre d overnight; H2O added; extd. (CH2Cl2); chromd. (silica gel, hexane/CH2Cl2, 1/2); elem. anal.;
DOI:10.1021/om300135f