Ir(ttp)H

Base Information

• Chemical Name: Ir(ttp)H
• CAS No.: 105139-33-1
• Molecular Formula: C₄₈H₃₇IrN₄
• Molecular Weight: 862.069
• Mol file: 105139-33-1.mol

Synonyms:Ir(ttp)H

Chemical Property of Ir(ttp)H

Chemical Property:

Purity/Quality:

Safty Information:

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• Hazard Codes: 

MSDS Files:

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Technology Process of Ir(ttp)H

There total 24 articles about Ir(ttp)H which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

hydrogenchloride (7647-01-0,15364-23-5) + (5,10,15,20-tetrakis(p-tolyl)porphyrinato)carbonyliridium(III) chloride (872415-81-1) → (hydrido)(5,10,15,20-tetrakis(p-tolyl)porphyrinato)iridium(III) (105139-33-1)

Guidance literature:

With NaBH₄; In tetrahydrofuran; sodium hydroxide; water; aq. NaOH; (under N2); soln. of NaBH4 in aq. NaOH and concd. HCl in H2O added to suspn. of Ir-complex in THF, heated at 70°C for 2 h, cooled in ice-water bath, HCl added, stirred; filtered, washed with H2O;

DOI:10.1021/om700751h

Reference yield: 84.0%

(5,10,15,20-tetrakis(p-tolyl)porphyrinato)carbonyliridium(III) chloride (872415-81-1) → (hydrido)(5,10,15,20-tetrakis(p-tolyl)porphyrinato)iridium(III) (105139-33-1) + potassium (5,10,15,20-tetrakis(p-tolyl)porphyrinato)iridate(I) (1215770-07-2)

Guidance literature:

With water; potassium hydroxide; In benzene-d6; at 120 ℃; for 5h; Darkness;

DOI:10.1021/om200251k

Reference yield: 71.0%

bromo(carbonyl)(5,10,15,20-tetrakis(p-tolyl)porphyrinato)iridium(III) (1280227-67-9) → (hydrido)(5,10,15,20-tetrakis(p-tolyl)porphyrinato)iridium(III) (105139-33-1) + potassium (5,10,15,20-tetrakis(p-tolyl)porphyrinato)iridate(I) (1215770-07-2)

Guidance literature:

With water; potassium hydroxide; In benzene-d6; at 120 ℃; for 5h; Darkness;

DOI:10.1021/om200251k

upstream raw materials:

water

(5,10,15,20-tetrakis(p-tolyl)porphyrinato)carbonyliridium(III) chloride

⁽²⁾H₈-toluene

hydrogenchloride

Downstream raw materials:

(5,10,15,20-tetrakis(p-tolyl)porphyrinato)(methyl)iridium(III)

(5,10,15,20-tetrakis(p-tolyl)porphyrinato)(benzyl)iridium(III)

(5,10,15,20-tetrakis(p-tolyl)porphyrinato)(benzyl)iridium(III)

[Ir(5,10,15,20-tetra-p-tolylporphyrinato dianion)(SiEt₃)]