[Pt(4,4'-dimethyl-2,2'-bipyridine)(C_.tplbond.CC₆H₅)]

Base Information

• Chemical Name: [Pt(4,4'-dimethyl-2,2'-bipyridine)(C_.tplbond.CC₆H₅)]
• CAS No.: 198711-11-4
• Molecular Formula: C₂₈H₂₂N₂Pt
• Molecular Weight: 581.576
• Mol file: 198711-11-4.mol

Synonyms:[Pt(4,4'-dimethyl-2,2'-bipyridine)(C_.tplbond.CC₆H₅)]

Chemical Property of [Pt(4,4'-dimethyl-2,2'-bipyridine)(C_.tplbond.CC₆H₅)]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [Pt(4,4'-dimethyl-2,2'-bipyridine)(C_.tplbond.CC₆H₅)]

There total 2 articles about [Pt(4,4'-dimethyl-2,2'-bipyridine)(C_.tplbond.CC₆H₅)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

dichlorido(4,4'-dimethyl-2,2'-bipyridine)platinum(II) (54822-56-9) + phenylacetylene (536-74-3) → [Pt(4,4'-dimethyl-2,2'-bipyridine)(C.tplbond.CC6H5)] (198711-11-4)

Guidance literature:

With CuI; diisopropylamine; In dichloromethane; (N2); addn. of phenylacetylene to suspension of Pt complex and CuI in diisopropylamine/CH2Cl2 at 25 °C, stirring for 24 h; evapn. of volatiles in vac., residue solved in CH2Cl2, filtration through Al2O3, evapn. of solvent in vac.; elem. anal.;

DOI:10.1016/S0022-328X(03)00777-0

Reference yield:

[(cis-(4,4'-dimethyl-2,2'-bipyridine)platinum(II)(C.ident.CPh)2)AgPPh3]BF4*methylene dichloride → [Pt(4,4'-dimethyl-2,2'-bipyridine)(C.tplbond.CC6H5)] (198711-11-4) + ((CH3)C5NH3)2Pt(CCC6H5)P(C6H5)3(1+)*BF4(1-)=((CH3)C5NH3)2Pt(CCC6H5)P(C6H5)3BF4 (629613-42-9) + silver phenylacetylide (33440-88-9)

Guidance literature:

In dichloromethane; (N2); stirring of soln. of ((cis-(4,4'-dimethyl-2,2'-bipyridine)Pt(CCPh)2)AgPPh3)BF4 in CH2Cl2 for 24 h at 25 °C in the dark; pptn. of silver complex, decanted, reduction of solvent, addn. of n-pentane, crystn. 25 °C, manual sepn. of crystals;

DOI:10.1016/S0022-328X(03)00777-0

Reference yield: 85.0%

silver tetrafluoroborate (14104-20-2) + [Pt(4,4'-dimethyl-2,2'-bipyridine)(C.tplbond.CC6H5)] (198711-11-4) + dichloromethane (75-09-2) → [cis-(4,4'-dimethyl-2,2'-bipyridine)platinum(II)(C.ident.CPh)2]AgFBF4*methylene dichloride

Guidance literature:

In dichloromethane; (N2); addn. of AgBF4 to soln. of cis-(4,4'-dimethyl-2,2'-bipyridine)Pt(CCPh)2 in CH2Cl2 at 25 °C in the dark, stirring for 12 h; crystn., removal of solvent, washed twice with CH2Cl2 and n-pentane, dried in vac.; elem. anal.;

DOI:10.1016/S0022-328X(03)00777-0

upstream raw materials:

dichlorido(4,4'-dimethyl-2,2'-bipyridine)platinum(II)

phenylacetylene

Downstream raw materials:

[((CH₃C₅H₃N)2)Pt(CCC₆H₅)2]HgI₂

(cis-[Pt(4,4'-dimethyl-2,2'-bipyridine)(μ-σ,π-phenylethynyl)2])(AgPF6)

(cis-[Pt(4,4'-dimethyl-2,2'-bipyridine)(μ-σ,π-phenylethynyl)2])(AgB(C6H5)4)

((CH₃)C₅NH₃)2Pt(CCC₆H₅)P(C₆H₅)3⁽¹⁺⁾*BF₄^(1-)=((CH₃)C₅NH₃)2Pt(CCC₆H₅)P(C₆H₅)3BF₄

Refernces

• 1、 James, Stuart L.,Younus, Muhummad,Raithby, Paul R.,Lewis, Jack. "Platinum bis-acetylide complexes with the 4,4′-dimethyl-2,2′-bipyridyl ligand". . p. 233 - 235. Retrieved 2007/10/03.