N,N-Dimethyltetradecylamine

Base Information

• Chemical Name: N,N-Dimethyltetradecylamine
• CAS No.: 112-75-4
• Molecular Formula: C16H35N
• Molecular Weight: 241.461
• Hs Code.: 2921199090
• European Community (EC) Number: 204-002-4
• NSC Number: 78319
• UN Number: 2735
• UNII: 5E4O85D8T2
• DSSTox Substance ID: DTXSID4026927
• Nikkaji Number: J121.780A
• Wikidata: Q24817433
• RXCUI: 2360890
• ChEMBL ID: CHEMBL1886777
• Mol file: 112-75-4.mol

Synonyms:N,N-Dimethyltetradecylamine;112-75-4;N,N-dimethyltetradecan-1-amine;N,N-Dimethylmyristylamine;DIMETHYL MYRISTAMINE;Tetradecyldimethylamine;1-Tetradecanamine, N,N-dimethyl-;1-(Dimethylamino)tetradecane;Dimethyltetradecylamine;Dimethylmyristamine;Dimethylmyristylamine;Myristyldimethylamine;Dimethyl(tetradecyl)amine;N,N-Dimethyl-N-tetradecylamine;Armeen DM 14D;Dimethyl-n-tetradecylamine;N,N-Dimethyl-1-tetradecanamine;Tetradecylamine, N,N-dimethyl-;N,N-Dimethyltetradecanamine;Myristyl dimethyl amine;Genamin 14R302D;Adma 14;IPL 30;NSC 78319;Armine DM14D;Dimethyl myristylamine;HSDB 2785;tetradecyl dimethylamine;N-Tetradecyldimethylamine;EINECS 204-002-4;UNII-5E4O85D8T2;DTXSID4026927;5E4O85D8T2;1-Tetradecanamine, N,N-dimethyly-;NSC-78319;EC 204-002-4;Onamine 14;Farmin DM 4098;dimethyl-tetradecyl-amine;N N-Dimethylmyristylamine;BARLENE 14S;Nissan Tertiary Amine MB;N,N-dimethyltetradecylamin;BARLENE 14;N N-Dimethyltetradecylamine;Tetradecylamine,N-dimethyl-;dimethylmono-n-tetradecylamine;SCHEMBL108754;1-Tetradecanamine,N-dimethyl-;N-tetradecyl-N,N-dimethylamine;DTXCID806927;N N-Dimethyl-1-tetradecanamine;N N-Dimethyl-N-tetradecylamine;N, N-dimetil-N-tetradecilamina;N, N-dimetil-1-tetradecanamina;CHEMBL1886777;N,N-dimethyl-N-tetradecyl amine;Tetradecilamina, N, N-dimetil-;tetradecylcamine, N,N-dimethyl-;1-Tetradecanamina, N,N-dimetil-;N,N-Dimethyl-1-tetradecanamine #;DIMETHYL MYRISTAMINE [HSDB];DIMETHYL MYRISTAMINE [INCI];NSC78319;Tox21_202738;MFCD00053736;MYRISTYLAMINE, N,N-DIMETHYL-;AKOS015914872;AT 1495;NCGC00164288-01;NCGC00260286-01;AS-80853;CAS-112-75-4;TETRADECAN-1-AMINE, N,N-DIMETHYL-;Tetradecylamine NN-dimethyl-(6CI7CI8CI);LS-163821;CS-0196512;D1844;FT-0629561;F71248;A802644;W-109418;Q24817433;N,N-Dimethyltetradecylamine, technical, >=95% (GC/NT)

Chemical Property of N,N-Dimethyltetradecylamine

Chemical Property:

• Appearance/Colour: Liquid
• Vapor Pressure: 0.00147mmHg at 25°C
• Melting Point: -3°C
• Refractive Index: n20/D 1.441
• Boiling Point: 296 °C at 760 mmHg
• PKA: 9.78±0.28(Predicted)
• Flash Point: 124.9 °C
• PSA: 3.24000
• Density: 0.805 g/cm³
• LogP: 5.24910
• Storage Temp.: Room Temperature
• Solubility.: Chloroform (Slightly), Hexane (Slightly), Methanol (Slightly)
• XLogP3: 6.9
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 13
• Exact Mass: 241.276950121
• Heavy Atom Count: 17
• Complexity: 132
• Transport DOT Label: Corrosive

Purity/Quality:

99% ^*data from raw suppliers

N,N-Dimethyltetradecylamine ^*data from reagent suppliers

Safty Information:

• Pictogram(s): C
• Hazard Codes: C
• Statements: 22-34
• Safety Statements: 26-36/37/39-45

MSDS Files:

SDS file from LookChem

Useful:

• Chemical Classes: Nitrogen Compounds -> Amines, Aliphatic
• Canonical SMILES: CCCCCCCCCCCCCCN(C)C
• Uses: N,N-Dimethyltetradecylamine (cas# 112-75-4) is a compound useful in organic synthesis. N,N-Dimethyltetradecylamine has been used for the synthesis of 1,6-bis(N,N-tetradecyl dimethylammonium adipate), a counterion coupled gemini (cocogem) surfactant. It may also be used in the following studies:For the isolation of recombinant botulinum neurotoxin fragments in the yeast Pichia pastoris by cell permeabilization method.Synthesis of gemini surfactants belonging to the series of alkanediyl-α,ω-bis-(dimethylalkyl ammonium bromide, which were evaluated as corrosion inhibitors of iron in hydrochloric acid medium.Preparation of cationic gemini surfactant of the type N-alkanediyl 1,2-ethane bis(dimethyl ammonium bromide).

Technology Process of N,N-Dimethyltetradecylamine

There total 3 articles about N,N-Dimethyltetradecylamine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.08%

1-Bromotetradecane (112-71-0) + dimethyl amine (124-40-3) → N,N-dimethyl-n-tetradecylamine (112-75-4)

Guidance literature:

In ethanol; water; at 80 ℃; for 24h;

DOI:10.1016/j.molliq.2017.01.063

Reference yield:

methanol (67-56-1) + tetradecylamine (2016-42-4) → N,N-dimethyl-n-tetradecylamine (112-75-4)

Guidance literature:

With platinum on carbon; sodium hydroxide; at 150 ℃; for 36h; under 750.075 Torr; Inert atmosphere; Autoclave;

DOI:10.1016/j.jcat.2019.01.027

Reference yield:

→ N,N-dimethyl-n-tetradecylamine (112-75-4)

Guidance literature:

N,N-Dimethylamid, entspr. Kohlenwasserstoff, H2;

upstream raw materials:

1-Bromotetradecane

dimethyl amine

methanol

tetradecylamine

Downstream raw materials:

[2-(2-chloro-phenoxy)-ethyl]-dimethyl-tetradecyl-ammonium; bromide

(2-biphenyl-4-yloxy-ethyl)-dimethyl-tetradecyl-ammonium; bromide

(2-biphenyl-2-yloxy-ethyl)-dimethyl-tetradecyl-ammonium; bromide

[2-(3-chloro-biphenyl-2-yloxy)-ethyl]-dimethyl-tetradecyl-ammonium; bromide

Refernces

• 1、 Zhang, Ting,Cao, Xianfei,Wang, Xuchun,Song, Changchun. "Synthesis, surface activity and thermodynamic properties of cationic gemini surfactants with diester and rigid spacers". . p. 505 - 510. Retrieved 2017/02/05.