NiCl₂ * 2,6-diacetylpyridinebis(anil)

Base Information

• Chemical Name: NiCl₂ * 2,6-diacetylpyridinebis(anil)
• CAS No.: 55157-58-9
• Molecular Formula: C₂₁H₁₉Cl₂N₃Ni
• Molecular Weight: 442.998
• Mol file: 55157-58-9.mol

Synonyms:NiCl₂ * 2,6-diacetylpyridinebis(anil)

Chemical Property of NiCl₂ * 2,6-diacetylpyridinebis(anil)

Chemical Property:

Purity/Quality:

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Technology Process of NiCl₂ * 2,6-diacetylpyridinebis(anil)

There total 1 articles about NiCl₂ * 2,6-diacetylpyridinebis(anil) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

2,6-Diacetylpyridine (1129-30-2) + aniline (62-53-3) + nickel dichloride (83864-14-6) → NiCl2 * 2,6-diacetylpyridinebis(anil) (55157-58-9)

Guidance literature:

In tetrahydrofuran; at 85 ℃; for 24h; Sealed tube; Inert atmosphere;

DOI:10.1002/cjoc.201800359

Reference yield: 90.0%

NiCl2 * 2,6-diacetylpyridinebis(anil) (55157-58-9) + tetraethylammonium phenylthiolate (3193-72-4) → Ni((C6H5NC(CH3))2(C5H3N))(C6H5S)2*C2H5OH

Guidance literature:

In ethanol; (N2); stirring (1 h); filtration; elem. anal.;

DOI:10.1021/ja00110a013

Reference yield: 80.0%

NiCl2 * 2,6-diacetylpyridinebis(anil) (55157-58-9) + tetraethylammonium phenylthiolate (3193-72-4) + acetonitrile (75-05-8,26809-02-9) → Ni(C6H5NCCH3)2C5H3N(SC6H5)2*CH3CN (144588-60-3)

Guidance literature:

In acetonitrile; treatment of Ni-complex with 2.2 equiv. of (Et4N)SPh;

upstream raw materials:

2,6-Diacetylpyridine

aniline

nickel dichloride

Downstream raw materials:

Ni(C₆H₅NCCH₃)2C₅H₃N(SC₆H₅)2*CH₃CN