Disilanyl

Base Information

• Chemical Name: Disilanyl
• CAS No.: 73151-72-1
• Molecular Formula: H6Si2
• Molecular Weight: 61.2107
• Wikidata: Q27113889
• Mol file: 73151-72-1.mol

Synonyms:Disilanyl;73151-72-1;CHEBI:30593;Si2H5(.);pentahydridodisilicon(Si--Si)(.);(Si2H5)(.);Q27113889

Chemical Property of Disilanyl

Chemical Property:

• PSA: 0.00000
• LogP: -2.10010
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 60.99297823
• Heavy Atom Count: 2
• Complexity: 0

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: [SiH3][SiH2]

Technology Process of Disilanyl

There total 5 articles about Disilanyl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

disilane (1590-87-0) → silyl (7440-21-3) + disilyl radical (73151-72-1,1590-87-0) + monosilane (7440-21-3)

Guidance literature:

With hydrogen; In gaseous matrix; Irradiation (UV/VIS); H atoms were generated by Hg-sensitized photolysis of H2, He-matrix; rate consts. for substitution H + Si2H6 -> SiH4 + SiH3 and abstraction H + Si2H6 -> H2 + Si2H5 were detd. with the pulse photolysis-resonance absorption method; Kinetics;

DOI:10.1021/om00137a030

Reference yield:

silyl (7440-21-3) + disilane (1590-87-0) → disilyl radical (73151-72-1,1590-87-0) + monosilane (7440-21-3)

Guidance literature:

In gas; Irradiation (UV/VIS); Kinetics;

DOI:10.1063/1.461707

Reference yield:

disilane (1590-87-0) + deuterium (16873-17-9,12184-84-8) → silyl (7440-21-3) + silane (13587-51-4) + disilyl radical (73151-72-1,1590-87-0) + deuterium hydride

Guidance literature:

In gas; D atoms were generated by Hg-sensitized photolysis of D2; ratio of rate consts. for substitution D + Si2H6 -> SiH3D + SiH3 and abstraction D + Si2H6 -> HD + Si2H5 was detd. by stationary photolysis (measuring the product ratio SiH3D/HD); reaction products were analyzed by mass spectrometry and by gas chromy.; Kinetics;

DOI:10.1021/om00137a030

upstream raw materials:

disilane

deuterium

silicon monohydride

monosilane