4-(pyridine-2-yl)-thiazole-2-yl 2,3,4,6-tetra-O-benzyl-1-thio-β-D-glucopyranoside

Base Information

Chemical Name:4-(pyridine-2-yl)-thiazole-2-yl 2,3,4,6-tetra-O-benzyl-1-thio-β-D-glucopyranoside
CAS No.:1095998-26-7
Molecular Formula:C₄₂H₄₀N₂O₅S₂
Molecular Weight:716.922
Hs Code.:

Synonyms:4-(pyridine-2-yl)-thiazole-2-yl 2,3,4,6-tetra-O-benzyl-1-thio-β-D-glucopyranoside

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Chemical Property of 4-(pyridine-2-yl)-thiazole-2-yl 2,3,4,6-tetra-O-benzyl-1-thio-β-D-glucopyranoside

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Technology Process of 4-(pyridine-2-yl)-thiazole-2-yl 2,3,4,6-tetra-O-benzyl-1-thio-β-D-glucopyranoside

There total 1 articles about 4-(pyridine-2-yl)-thiazole-2-yl 2,3,4,6-tetra-O-benzyl-1-thio-β-D-glucopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.0%

: 1095998-24-5
4-(pyridin-2-yl)thiazole-2-yl-1-thio-β-D-glucopyranoside

: 100-39-0
benzyl bromide

: 1095998-26-7
4-(pyridine-2-yl)-thiazole-2-yl 2,3,4,6-tetra-O-benzyl-1-thio-β-D-glucopyranoside

Guidance literature:: With sodium hydride; In N,N-dimethyl-formamide; mineral oil; at 0 - 20 ℃;
DOI:10.1039/b810569c

Reference yield: 67.0%

: 14104-20-2
silver tetrafluoroborate

: 1095998-26-7
4-(pyridine-2-yl)-thiazole-2-yl 2,3,4,6-tetra-O-benzyl-1-thio-β-D-glucopyranoside

: fac-[(PtMe₃I)4]

: 67-64-1
acetone

: fac-[PtMe3(4-(pyridine-2-yl)-thiazole-2-yl 2,3,4,6-tetra-O-benzyl-1-thio-β-D-glucopyranoside)][BF4]

Guidance literature:: In acetone; byproducts: AgI; under Ar; a suspn. of Pt-contg. compd. (0.04 mmol) and AgBF4 (0.14 mmol)in acetone was stirred for 30 min under the absence of light; AgI was r emoved by filtration; a soln. of Pt-contg. compd. was added to the ligand (0.14 mmol); after 5 h the vol. of the soln. was reduced in vac. and pentane was added; the solid was filtered, washed with pentane and dried in vac.;
DOI:10.1039/b927058b

Reference yield:

: 1095998-26-7
4-(pyridine-2-yl)-thiazole-2-yl 2,3,4,6-tetra-O-benzyl-1-thio-β-D-glucopyranoside

: 1095998-35-8
4-(pyridin-2-yl)thiazole-2-yl 2,3,4-tri-O-benzoyl-6-triphenylmethyl-1-thio-β-D-glucopyranoside

: 4-(pyridin-2-yl)thiazole-2-yl 2,3,4-tri-O-benzoyl-6-O-(2,3,4,6-tetra-O-benzyl-β-D-glucopyranosyl)-1-thio-β-D-glucopyranoside

: 1095998-52-9
4-(pyridin-2-yl)thiazole-2-yl 2,3,4-tri-O-benzoyl-6-O-(2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl)-1-thio-β-D-glucopyranoside

Guidance literature:: 4-(pyridin-2-yl)thiazole-2-yl 2,3,4-tri-O-benzoyl-6-triphenylmethyl-1-thio-β-D-glucopyranoside; With palladium(II) bromide; In 1,2-dichloro-ethane; at 20 ℃; Molecular sieve;

With water; trifluoroacetic acid; In dichloromethane; at 20 ℃; for 1h;

4-(pyridine-2-yl)-thiazole-2-yl 2,3,4,6-tetra-O-benzyl-1-thio-β-D-glucopyranoside; optical yield given as %de; Further stages;
DOI:10.1039/b810569c