(3S)-10-benzyloxy-3-hydroxy-1-p-toluenesulfonyloxydecane

Base Information

Chemical Name:(3S)-10-benzyloxy-3-hydroxy-1-p-toluenesulfonyloxydecane
CAS No.:151985-44-3
Molecular Formula:C₂₄H₃₄O₅S
Molecular Weight:434.597
Hs Code.:

Synonyms:(3S)-10-benzyloxy-3-hydroxy-1-p-toluenesulfonyloxydecane

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Chemical Property of (3S)-10-benzyloxy-3-hydroxy-1-p-toluenesulfonyloxydecane

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Technology Process of (3S)-10-benzyloxy-3-hydroxy-1-p-toluenesulfonyloxydecane

There total 10 articles about (3S)-10-benzyloxy-3-hydroxy-1-p-toluenesulfonyloxydecane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 59.0%

: 98-59-9
p-toluenesulfonyl chloride

: 151985-43-2
(3S)-10-benzyloxy-1,3-decanediol

: 151985-44-3
(3S)-10-benzyloxy-3-hydroxy-1-p-toluenesulfonyloxydecane

Guidance literature:: With sodium hydride; In N,N-dimethyl-formamide; at 0 ℃; for 1h;

Reference yield:

: 112-47-0
1,10-Decanediol

: 151985-44-3
(3S)-10-benzyloxy-3-hydroxy-1-p-toluenesulfonyloxydecane

Guidance literature:: Multi-step reaction with 9 steps

1: 40 percent / sodium hydride / tetrahydrofuran; dimethylformamide / 1.) 0 deg C, 1 h, 2.) room temperature, 12 h

2: 68 percent / Jones reagent

3: 98 percent

4: 46 percent / lithium diisopropylamide / tetrahydrofuran; hexane / 0.5 h / -78 °C

5: 74 percent / 30percent H₂O₂, sodium hydrocarbonate / tetrahydrofuran / 1.) 0 deg C, 2.) room temperature, 1 h

6: 93 percent / diisobutylaluminum hydride / CH₂Cl₂; toluene / 0.5 h / -78 °C

7: 74 percent / tetra-iso-propyl titanate, L-(+)-diethyl tartrate, molecular sieves 3A / CH₂Cl₂ / 3 h / -25 °C

8: 40 percent / sodium bis(2-methoxyethoxy)aluminum hydride, (+)-diisopropyl tartrate / tetrahydrofuran; toluene / 1.) 0 deg C, 2 h, 2.) room temperature, 72 h

9: 59 percent / sodium hydride / dimethylformamide / 1 h / 0 °C

With titanium(IV) isopropylate; jones reagent; L-(+)-diisopropyl tartrate; diethyl (2R,3R)-tartrate; 3 A molecular sieve; dihydrogen peroxide; sodium hydride; diisobutylaluminium hydride; sodium hydrogencarbonate; sodium bis(2-methoxyethoxy)aluminium dihydride; lithium diisopropyl amide; In tetrahydrofuran; hexane; dichloromethane; N,N-dimethyl-formamide; toluene;

Reference yield:

: 100-44-7
benzyl chloride

: 151985-44-3
(3S)-10-benzyloxy-3-hydroxy-1-p-toluenesulfonyloxydecane

Guidance literature:: Multi-step reaction with 9 steps

1: 40 percent / sodium hydride / tetrahydrofuran; dimethylformamide / 1.) 0 deg C, 1 h, 2.) room temperature, 12 h

2: 68 percent / Jones reagent

3: 98 percent

4: 46 percent / lithium diisopropylamide / tetrahydrofuran; hexane / 0.5 h / -78 °C

5: 74 percent / 30percent H₂O₂, sodium hydrocarbonate / tetrahydrofuran / 1.) 0 deg C, 2.) room temperature, 1 h

6: 93 percent / diisobutylaluminum hydride / CH₂Cl₂; toluene / 0.5 h / -78 °C

7: 74 percent / tetra-iso-propyl titanate, L-(+)-diethyl tartrate, molecular sieves 3A / CH₂Cl₂ / 3 h / -25 °C

8: 40 percent / sodium bis(2-methoxyethoxy)aluminum hydride, (+)-diisopropyl tartrate / tetrahydrofuran; toluene / 1.) 0 deg C, 2 h, 2.) room temperature, 72 h

9: 59 percent / sodium hydride / dimethylformamide / 1 h / 0 °C

With titanium(IV) isopropylate; jones reagent; L-(+)-diisopropyl tartrate; diethyl (2R,3R)-tartrate; 3 A molecular sieve; dihydrogen peroxide; sodium hydride; diisobutylaluminium hydride; sodium hydrogencarbonate; sodium bis(2-methoxyethoxy)aluminium dihydride; lithium diisopropyl amide; In tetrahydrofuran; hexane; dichloromethane; N,N-dimethyl-formamide; toluene;