Sodium feredetate

Base Information

• Chemical Name: Sodium feredetate
• CAS No.: 15708-41-5
• Deprecated CAS: 29507-61-7,36619-30-4,39458-91-8,52645-49-5,55648-23-2,5915-66-2,7487-54-9
• Molecular Formula: C10H12FeN2NaO8
• Molecular Weight: 367.051
• Hs Code.: 29224999
• European Community (EC) Number: 239-802-2,803-202-4
• UNII: 403J23EMFA
• DSSTox Substance ID: DTXSID5027774
• Nikkaji Number: J2.239.441J
• Wikipedia: Ferric_sodium_EDTA
• Wikidata: Q30314945
• NCI Thesaurus Code: C76827
• Mol file: 15708-41-5.mol

Synonyms:ammonium ferric edetate;EDTA Fe(III);EDTA ferric ammonium;Fe(III)-EDTA;Fe(III)-edta complex (1:1);Fe(III)-EDTA, ammonium salt;Fe(III)-EDTA, potassium salt;Fe(III)-EDTA, sodium salt;Fe(III)-EDTA, sodium salt, trihydrate;ferrate(1-), ((ethylenedinitrilo)tetraacetato)-, hydrogen;ferric EDTA;ferric sodium edetate;ferric-edta;hydrogen ((ethylenedinitrilo)tetraacetato)ferrate(III);iron(III) EDTA;Irostrene;monoferric edetate;NaFeEDTA;sodium feredetate;sodium iron EDTA;Sytron

Chemical Property of Sodium feredetate

Chemical Property:

• Appearance/Colour: yellow-brown powder
• Boiling Point: 614.2 °C at 760 mmHg
• Flash Point: 325.2 °C
• PSA: 167.00000
• Density: 1.781[at 20℃]
• LogP: -7.41250
• Storage Temp.: room temp
• Solubility.: Methanol (Slightly), Water (Slightly)
• Water Solubility.: soluble
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 10
• Rotatable Bond Count: 7
• Exact Mass: 366.984070
• Heavy Atom Count: 22
• Complexity: 293

Purity/Quality:

99%min ^*data from raw suppliers

Ethylenediaminetetraacetic Acid Ferric Sodium Salt Trihydrate ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36-37/39-36/37

MSDS Files:

SDS file from LookChem

Useful:

• Chemical Classes: Metals -> Organic Acids, Metal Salts
• Canonical SMILES: C(CN(CC(=O)[O-])CC(=O)[O-])N(CC(=O)[O-])CC(=O)[O-].[Na+].[Fe+3]
• Description: EDTA ferric sodium salt is the ferric sodium salt of EDTA (Ethylene Diamine Tetraacetic Acid). It is a broad-spectrum molluscicide that is capable of killing snails and slugs and protecting agricultural crops and garden plants. In particular, it can eliminate infestations of Cornu aspersum, the common garden snail. It takes effect through interacting with and destroying hemocyanin, a copper based compound existing in the blood of molluscs and anthropods that is engaged in carrying oxygen (play a similar role with hemoglobin invertebrates). It is capable of killing snails and slugs in a few days. It can also be used as a food fortifier and a source of iron to be supplemented to the foods for nutrition purposes.
• Uses: Used as a micronutrient fertilizer, an additive in the food industry, a catalyst in the chemical industry and bleaching agent in the photographic industry. Sodium Iron EDTA is often used in children nutrition as a source of iron.

Technology Process of Sodium feredetate

There total 3 articles about Sodium feredetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

ammonium iron(III) sulfate + disodium ethylenediamine tetraacetic acid (64-02-8,139-33-3,150-38-9,7379-28-4,17421-79-3,71705-16-3,116229-67-5) → sodium (ethylenediaminetetraacetato)ferrate(III) (15708-41-5)

Guidance literature:

With ammonium hydroxide; N,N-dimethyl-formamide; In water; Fe salt disolved in concd. soln. of Na salt in H2O, soln. of NH4OH added to pH 8-9, resulting soln. heated at 80-90°C for 10 min, filtered, mother liquor treated with DMF so as to maintain final molar ratio of 1:1 of DMF to H2O, stirred; filtration, washing with EtOH, drying at 110°C overnight;

DOI:10.1016/S0020-1693(00)86968-6

Reference yield:

ethylenediaminetetraacetic acid (60-00-4,94108-75-5) + iron(III) chloride (7705-08-0) + sodium hydrogencarbonate (144-55-8) → sodium (ethylenediaminetetraacetato)ferrate(III) (15708-41-5)

Guidance literature:

In water; H4EDTA, FeCl3 and H2O heated to 60°C with stirring under N2, after full dissolution proper carbonate added; filtered, redissolved in H2O. membrane dialysis, solid washed (acetone),dried (20 mTorr, 12 h); mass spect., TGA;

DOI:10.1016/j.jcat.2011.01.007

Reference yield:

Iron(III) nitrate nonahydrate + ethylenediaminetetraacetic acid (60-00-4,94108-75-5) + sodium hydrogencarbonate (144-55-8) → sodium (ethylenediaminetetraacetato)ferrate(III) (15708-41-5)

Guidance literature:

In water; H4EDTA, Fe(NO3)3 and H2O heated to 60°C with stirring under N2, after full dissolution proper carbonate added; filtered, redissolved in H2O. membrane dialysis, solid washed (acetone),dried (20 mTorr, 12 h); mass spect., TGA;

DOI:10.1016/j.jcat.2011.01.007

upstream raw materials:

disodium ethylenediamine tetraacetic acid

ethylenediaminetetraacetic acid

iron(III) chloride

sodium hydrogencarbonate

Refernces

• 1、 Prieto-Centurion, Dario,Notestein, Justin M.. "Surface speciation and alkane oxidation with highly dispersed Fe(III) sites on silica". . p. 103 - 110. Retrieved 2011.