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107-98-2

Basic Information
CAS No.: 107-98-2
Name: 1-Methoxy-2-propanol
Molecular Structure:
Molecular Structure of 107-98-2 (1-Methoxy-2-propanol)
Formula: C4H10O2
Molecular Weight: 90.14
Synonyms: 1-Methoxy-2-hydroxypropane;Dowtherm 209;Propylene glycol methyl ether;Propylenglykol-monomethylaether;Dowanol-33B;1-methoxypropan-2-ol;.alpha.-Propylene glycol monomethyl ether;2-Methoxy-1-methylethanol;2-Propanol,1-methoxy-;2-Propanol, 1-methoxy-;Propylene Glycol Monomethyl Ether(PM):;Propylene Glycol Monomethyl Ether;Methoxyisopropanol;
EINECS: 203-539-1
Density: 0.912 g/cm3
Melting Point: - 97 °C
Boiling Point: 118.5 °C at 760 mmHg
Flash Point: 33.9 °C
Solubility: soluble in water
Appearance: colourless liquid
Hazard Symbols: R10:;
Risk Codes: 10
Safety: 26-24/25
Transport Information: UN 3092 3/PG 3
PSA: 29.46000
LogP: 0.01360
Synthetic route

A

107-98-2

1-methoxy-2-propanol

B

75-56-9, 16033-71-9

methyloxirane

Conditions
ConditionsYield
With pyridine N-oxide; dihydrogen peroxide; methyltrioxorhenium(VII) In methanol; water at 40℃; under 11894.7 - 36201.3 Torr; for 3h;A 1.02%
B 98%
With pyridine; carbon dioxide; dihydrogen peroxide; methyltrioxorhenium(VII) In methanol; water at 25 - 40℃; under 36201.3 Torr; for 3h;A n/a
B 60.25%
With pyridine N-oxide; carbon dioxide; dihydrogen peroxide; methyltrioxorhenium(VII) In methanol; water at 25 - 40℃; under 36201.3 Torr; for 3 - 9h;A n/a
B 51.1%
With pyridine N-oxide; urea hydrogen peroxide adduct; methyltrioxorhenium(VII) In methanol; water at 30℃; under 12929 Torr;
67-56-1

methanol

75-56-9, 16033-71-9

methyloxirane

107-98-2

1-methoxy-2-propanol

Conditions
ConditionsYield
With sodium hydroxide at 120℃; for 0.116667h; Concentration; Temperature; Reagent/catalyst; Flow reactor;93%
With sodium methylate78%
With Al2O3/MgO composite at 120℃; Inert atmosphere;37.4%
67-56-1

methanol

75-56-9, 16033-71-9

methyloxirane

A

107-98-2

1-methoxy-2-propanol

B

1589-47-5

2-methoxypropanol

Conditions
ConditionsYield
With MCM-41-encapsulated cetyltrimethylammonium hydroxide at 110℃; for 3h; regioselective reaction;A 92%
B n/a
With boron trifluoride diethyl etherateA 36%
B 39%
at 200℃;

A

57-55-6

propylene glycol

B

107-98-2

1-methoxy-2-propanol

C

1589-47-5

2-methoxypropanol

D

75-56-9, 16033-71-9

methyloxirane

Conditions
ConditionsYield
With dihydrogen peroxide; titanium-silicate In methanol at 40℃;A n/a
B n/a
C n/a
D 92%
With dihydrogen peroxide; titanium-silicate In methanol at 40℃;A n/a
B n/a
C n/a
D 78%
With dihydrogen peroxide; titanium-silicate In water at 30 - 80℃; under 18751.9 Torr; pH=4.5;A n/a
B n/a
C n/a
D 61%
57-55-6

propylene glycol

74-88-4

methyl iodide

107-98-2

1-methoxy-2-propanol

Conditions
ConditionsYield
With iron(III) perchlorate at 20℃; for 24h; neat (no solvent);85%
With potassium In tetrahydrofuran for 2h; Heating;58%
930-37-0

glycidyl methyl ether

107-98-2

1-methoxy-2-propanol

Conditions
ConditionsYield
With Bu3Sn(HMPA)I; tri-n-butyl-tin hydride In tetrahydrofuran at 40℃; for 24h;75%

A

57-55-6

propylene glycol

B

107-98-2

1-methoxy-2-propanol

C

75-56-9, 16033-71-9

methyloxirane

Conditions
ConditionsYield
With pyridine N-oxide; dihydrogen peroxide; methyltrioxorhenium(VII) In methanol; water at 40℃; under 36201.3 Torr; for 3h;A 0.59%
B 1.85%
C 72.73%
With dihydrogen peroxide In methanol at 49.84℃; under 5250.53 Torr; Green chemistry;
67-56-1

methanol

124-38-9

carbon dioxide

75-56-9, 16033-71-9

methyloxirane

A

108-32-7

1,2-propylene cyclic carbonate

B

57-55-6

propylene glycol

C

107-98-2

1-methoxy-2-propanol

D

1589-47-5

2-methoxypropanol

E

616-38-6

carbonic acid dimethyl ester

Conditions
ConditionsYield
With 6,7,9,10,12,13,20,21-octahydrodibenzo[b,h][1,4,7,10,13,16]hexaoxacyclooctadecine; potassium chloride at 130℃; under 15001.5 Torr; for 8h; Reagent/catalyst; Autoclave; High pressure;A 69.2%
B 12.5%
C n/a
D n/a
E 13.2%
With 6,7,9,10,12,13,20,21-octahydrodibenzo[b,h][1,4,7,10,13,16]hexaoxacyclooctadecine; potassium bromide at 130℃; under 15001.5 Torr; for 8h; Reagent/catalyst; Autoclave; High pressure;A 62.9%
B 14.4%
C n/a
D n/a
E 12.5%
With potassium bromide at 130℃; under 15001.5 Torr; for 8h; Autoclave; High pressure;A 44.1%
B 6.7%
C n/a
D n/a
E 5.8%
67-56-1

methanol

75-56-9, 16033-71-9

methyloxirane

A

107-98-2

1-methoxy-2-propanol

B

1589-47-5

2-methoxypropanol

C

127-00-4

1-Chloro-2-propanol

Conditions
ConditionsYield
With Cu(L-Asp)(1,2-bis(4-pyridyl)ethylene)0.5(H2O)0.5(MeOH)0.5 at 25℃;A 56%
B 40%
C 4%
With Cu(L-Asp)(1,2-bis(4-pyridyl)ethylene)0.5(H2O)0.5(MeOH)0.5 at 60℃;A 49%
B 47%
C 4%
67-56-1

methanol

124-38-9

carbon dioxide

75-56-9, 16033-71-9

methyloxirane

A

108-32-7

1,2-propylene cyclic carbonate

B

107-98-2

1-methoxy-2-propanol

C

1589-47-5

2-methoxypropanol

Conditions
ConditionsYield
With lithium iodide at 130℃; under 15001.5 Torr; for 8h; Reagent/catalyst; Autoclave; High pressure;A 54.8%
B n/a
C n/a
With potassium carbonate at 100℃; for 6h; Supercritical conditions; Green chemistry;A 35.6%
B n/a
C n/a
67-56-1

methanol

124-38-9

carbon dioxide

75-56-9, 16033-71-9

methyloxirane

A

108-32-7

1,2-propylene cyclic carbonate

B

57-55-6

propylene glycol

C

107-98-2

1-methoxy-2-propanol

D

1589-47-5

2-methoxypropanol

Conditions
ConditionsYield
With lithium bromide at 130℃; under 15001.5 Torr; for 8h; Autoclave; High pressure;A 52.4%
B 5.7%
C n/a
D n/a
57-55-6

propylene glycol

A

107-98-2

1-methoxy-2-propanol

B

1589-47-5

2-methoxypropanol

Conditions
ConditionsYield
With H(+)-zeolite-X In benzene at 25℃; for 0.5h; Product distribution; further alcohols, thiols, aminoalcohols; further catalyst;A 51%
B 33%
With H(+)-zeolite-X In benzene at 25℃; for 0.5h;A 51 % Chromat.
B 33 % Chromat.
With sulfuric acid In benzene at 25℃; for 0.5h;A 37 % Chromat.
B 38 % Chromat.
5878-19-3

Methoxyacetone

107-98-2

1-methoxy-2-propanol

Conditions
ConditionsYield
With nickel at 140℃; under 294203 Torr; Hydrogenation;
With hydrogen; In diethylene glycol dimethyl ether; water at 30℃; under 735.5 Torr; for 20h;
124-41-4

sodium methylate

75-56-9, 16033-71-9

methyloxirane

107-98-2

1-methoxy-2-propanol

1072-47-5

4-methyl-1,3-dioxolane

A

107-98-2

1-methoxy-2-propanol

B

1589-47-5

2-methoxypropanol

Conditions
ConditionsYield
With lithium aluminium tetrahydride; boron trichloride 1.) CH2Cl2, 10 min, 2.) Et2O, 30 min; Yield given. Multistep reaction. Yields of byproduct given. Title compound not separated from byproducts;
627-40-7

methylallylether

A

71-23-8

propan-1-ol

B

107-98-2

1-methoxy-2-propanol

C

1589-49-7

methoxypropanol

Conditions
ConditionsYield
With sodium hydroxide; 9-borabicyclo[3.3.1]nonane dimer; dihydrogen peroxide Product distribution; 1) THF, 25 deg C, 2 h;A 1.5 % Chromat.
B n/a
C 94 % Chromat.
627-40-7

methylallylether

A

107-98-2

1-methoxy-2-propanol

B

1589-49-7

methoxypropanol

Conditions
ConditionsYield
With sodium hydroxide; sodium tetrahydroborate; mercury(II) diacetate 1) water, THF, 30 min, 2) ca. 0.5 h; Yield given. Multistep reaction. Yields of byproduct given;
With sodium hydroxide; mercury(II) diacetate In tetrahydrofuran; water Product distribution; 1) 30 min, 2) ca. 0.5 h;
67-56-1

methanol

75-56-9, 16033-71-9

methyloxirane

A

107-98-2

1-methoxy-2-propanol

B

20324-32-7

propylene glycol monomethyl ether dimer

Conditions
ConditionsYield
With sodium hydroxide at 85℃; Heating; Yield given. Yields of byproduct given;
With sodium hydroxide at 85℃; Heating; Yield given. Yields of byproduct given;
23465-33-0

1-bromo-2-methoxypropane

A

107-98-2

1-methoxy-2-propanol

B

1589-47-5

2-methoxypropanol

Conditions
ConditionsYield
at 100℃;
Reaxys ID: 11354065

Reaxys ID: 11354065

A

107-98-2

1-methoxy-2-propanol

B

1589-47-5

2-methoxypropanol

Conditions
ConditionsYield
Purification / work up; Industry scale;

A

57-55-6

propylene glycol

B

107-98-2

1-methoxy-2-propanol

C

74-98-6

propane

D

1589-47-5

2-methoxypropanol

E

75-56-9, 16033-71-9

methyloxirane

Conditions
ConditionsYield
With dihydrogen peroxide; titanium silicate In methanol at 59℃; under 18751.9 Torr; Product distribution / selectivity;
67-56-1

methanol

A

57-55-6

propylene glycol

B

107-98-2

1-methoxy-2-propanol

C

74-98-6

propane

D

1589-47-5

2-methoxypropanol

E

75-56-9, 16033-71-9

methyloxirane

Conditions
ConditionsYield
With ammonia; dihydrogen peroxide; titanium-silicate catalyst In water at 41 - 59℃; under 18751.9 Torr; pH=4.5; Product distribution / selectivity; Continuously procces;
With water; hydrogen; oxygen; Pd-Bi/TiO2; tegafur at 60℃; under 16274.9 Torr; for 18h; pH=6; Product distribution / selectivity; aqueous ammonium phosphate buffer;
With water; hydrogen; oxygen; Pd-Au/TiO2; tegafur at 60℃; under 16274.9 Torr; for 18h; pH=6; Product distribution / selectivity; aqueous ammonium phosphate buffer;
With water; hydrogen; oxygen; Pd-Bi-Au/TiO2; tegafur at 60℃; under 16274.9 Torr; for 18h; pH=6; Product distribution / selectivity; aqueous ammonium phosphate buffer;
With ammonium acetate; hydrogen; oxygen at 60℃; under 56255.6 Torr; for 12h; Catalytic behavior; Reagent/catalyst; Temperature; Autoclave; Supercritical conditions;A n/a
B n/a
C n/a
D n/a
E 11.8 %Chromat.
7440-32-6

titanium

98-85-1, 13323-81-4

1-Phenylethanol

A

107-98-2

1-methoxy-2-propanol

B

1589-47-5

2-methoxypropanol

Conditions
ConditionsYield
With dihydrogen peroxide In methanol
67-56-1

methanol

A

3,6-dioxa-2,4-dimethyl-1-heptanol

B

57-55-6

propylene glycol

C

108-61-2

2,2'-oxydipropanol

D

107-98-2

1-methoxy-2-propanol

E

74-98-6

propane

F

1589-47-5

2-methoxypropanol

G

75-56-9, 16033-71-9

methyloxirane

Conditions
ConditionsYield
With hydrogen; oxygen; Pd/TS-1 In water at 60℃; under 16274.9 Torr; pH=6; Product distribution / selectivity; ammonium phosphate buffer;
5878-19-3

Methoxyacetone

67-63-0

isopropyl alcohol

A

107-98-2

1-methoxy-2-propanol

B

67-64-1

acetone

Conditions
ConditionsYield
With Tri-tert-butylaluminium; trifluoroacetic acid In toluene at 60℃; for 24h; Meerwein-Ponndorf-Verley reduction; Inert atmosphere;
7778-85-0

1,2-dimethoxypropane

A

74-87-3

methylene chloride

B

26198-63-0, 78-87-5

1,2-Dichloropropane

C

107-98-2

1-methoxy-2-propanol

D

1589-47-5

2-methoxypropanol

Conditions
ConditionsYield
Stage #1: 1,2-dimethoxypropane With dichloromethane; tungsten(VI) chloride In Chloroform-D at 100℃; for 3h;
Stage #2: With water In Chloroform-D at -20℃;
67-56-1

methanol

124-38-9

carbon dioxide

75-56-9, 16033-71-9

methyloxirane

A

108-32-7

1,2-propylene cyclic carbonate

B

107-98-2

1-methoxy-2-propanol

C

616-38-6

carbonic acid dimethyl ester

Conditions
ConditionsYield
With Br(1-)*C14H33N2(1+) at 170℃; under 15001.5 - 37503.8 Torr; for 8h; Autoclave;
75-56-9, 16033-71-9

methyloxirane

A

57-55-6

propylene glycol

B

107-98-2

1-methoxy-2-propanol

C

1589-47-5

2-methoxypropanol

Conditions
ConditionsYield
With 0.5% Pt/Al2O3; dihydrogen peroxide at 59.84℃; under 3750.38 Torr; for 2h; Inert atmosphere; Autoclave;
107-98-2

1-methoxy-2-propanol

124-63-0

methanesulfonyl chloride

24590-51-0

(+/-)-(methoxyprop-2-yl) methanesulphonate

Conditions
ConditionsYield
With triethylamine In dichloromethane at 0 - 20℃; for 1h;100%
With pyridine at -5℃;
936247-35-7

5-chloro-2-nitropyridin-3-ol

107-98-2

1-methoxy-2-propanol

1144110-19-9

5-chloro-3-(2-methoxy-1-methyl-ethoxy)-2-nitro-pyridine

Conditions
ConditionsYield
With di-tert-butyl-diazodicarboxylate; triphenylphosphine In tetrahydrofuran at 0℃; for 5h;100%
107-98-2

1-methoxy-2-propanol

700-36-7

2-bromo-4-fluoronitrobenzene

943247-79-8

2-bromo-4-(2-methoxy-1-methylethoxy)-1-nitrobenzene

Conditions
ConditionsYield
Stage #1: 1-methoxy-2-propanol With sodium hydride In N,N-dimethyl-formamide at 0℃; for 0.5h;
Stage #2: 2-bromo-4-fluoronitrobenzene In N,N-dimethyl-formamide at 0 - 20℃; for 1h;
100%
17464-88-9

1,3,4,6-tetrakis(methoxymethyl)glycoluril

107-98-2

1-methoxy-2-propanol

1,3,4,6-tetrakis(1'-methyl-2'-methoxy)ethoxymethylglycoluril

Conditions
ConditionsYield
With Amberlyst 15 resin at 60℃; for 17h; Catalytic behavior; Reagent/catalyst;99.8%
With AMBERLYST at 25 - 60℃; under 80 - 100 Torr; for 7h;
107-98-2

1-methoxy-2-propanol

5878-19-3

Methoxyacetone

Conditions
ConditionsYield
99.4%
With 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; trichloroisocyanuric acid; sodium hydrogencarbonate In dichloromethane at 0 - 10℃; for 3.5h; Temperature;97.8%
With 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; chlorine; sodium carbonate In dichloromethane at 0 - 10℃; for 3.5h; Reagent/catalyst; Temperature;97.6%
107-98-2

1-methoxy-2-propanol

61706-54-5

N-(chloromethyl)-N-(2,6-dimethylphenyl)-α-chloroacetamide

83447-95-4

2',6'-Dimethyl-N-(2-Methoxy-1-Methylethoxymethyl) 2-Chloroacetanilide

Conditions
ConditionsYield
In 1,2-dichloro-ethane99.1%
(S,S)-Co(salen)

(S,S)-Co(salen)

107-98-2

1-methoxy-2-propanol

106-89-8

epichlorohydrin

62-23-7

4-nitro-benzoic acid

60827-45-4

(S)-3-chloropropan-1,2-diol

Conditions
ConditionsYield
In water99%
107-98-2

1-methoxy-2-propanol

N-(2-ethyl-6-methylphenyl)-4-nitrobenzenesulfonamide

C18H22N2O5S

Conditions
ConditionsYield
With di-isopropyl azodicarboxylate; triphenylphosphine In toluene at 50℃; for 2h; Temperature; Cooling with ice;99%
With di-isopropyl azodicarboxylate; triphenylphosphine In toluene at 50℃; for 2h; Cooling with ice;62 %Chromat.
With di-isopropyl azodicarboxylate; triphenylphosphine In toluene at 50℃; for 2h; Cooling with ice;62 %Chromat.
107-98-2

1-methoxy-2-propanol

589-18-4

4-Methylbenzyl alcohol

1-(2-methoxy-1-methyl-ethoxymethyl)-4-methyl-benzene

Conditions
ConditionsYield
With ytterbium(III) triflate at 140℃; for 20h;97%
107-98-2

1-methoxy-2-propanol

627-40-7

methylallylether

Conditions
ConditionsYield
With zirconium(IV) oxide at 100℃; for 3h; Temperature; Reagent/catalyst;96.6%
85-44-9

phthalic anhydride

107-98-2

1-methoxy-2-propanol

C12H14O5

Conditions
ConditionsYield
With dmap In 2-methoxy-ethanol96%
1-methoxy-2-propanol (propylene glycol monomethylether)

1-methoxy-2-propanol (propylene glycol monomethylether)

107-98-2

1-methoxy-2-propanol

37721-75-8

tetrabromo-p-cresol

74-95-3

1,2-dibromomethane

bis(tetrabromo-4-methylphenoxy)-methane

Conditions
ConditionsYield
With sodium hydroxide In water95.3%
107-98-2

1-methoxy-2-propanol

179898-34-1

3-bromo-5-fluorobenzonitrile

883907-45-7

3-bromo-5-(2-methoxy-1-methylethoxy)benzonitrile

Conditions
ConditionsYield
Stage #1: 1-methoxy-2-propanol With sodium hexamethyldisilazane In N,N-dimethyl-formamide at 25℃; for 0.25h;
Stage #2: 3-bromo-5-fluorobenzonitrile In N,N-dimethyl-formamide at 23 - 27℃; for 0.583333h;
95%

trimethylaluminium dimer

107-98-2

1-methoxy-2-propanol

[(CH3)2Al(μ-O-CH(CH3)CH2-OCH3)]2

Conditions
ConditionsYield
In pentane byproducts: CH4; Ar-atmosphere; dropwise addn. of ligand to AlMe3 at -78°C, stirring for 2 h, then at room temp. for 12 h; solvent removal (vac.), sublimation (110°C/0.1 mbar); elem. anal.;94%
13734-41-3

t-Boc-L-valine

107-98-2

1-methoxy-2-propanol

(2S)-1-methoxypropan-2-yl 2-((tert-butoxycarbonyl)amino)-3-methylbutanoate

Conditions
ConditionsYield
With benzotriazol-1-ol; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride; N-ethyl-N,N-diisopropylamine In N,N-dimethyl-formamide at 20℃;94%
107-98-2

1-methoxy-2-propanol

N-(2-acetyl-6-methylphenyl)-2-nitrobenzenesulfonamide

N-(2-acetyl-6-methylphenyl)-N-(1-methoxypropan-2-yl)-2-nitrobenzenesulfonamide

Conditions
ConditionsYield
With di-isopropyl azodicarboxylate; triphenylphosphine In tetrahydrofuran; dichloromethane at 0 - 20℃; Mitsunobu Displacement; Inert atmosphere;90%
107-98-2

1-methoxy-2-propanol

1445-79-0

trimethyl gallium

[(CH3)2Ga(μ-O-CH(CH3)CH2-OCH3)]2

Conditions
ConditionsYield
In pentane byproducts: CH4; Ar-atmosphere; dropwise addn. of ligand to GaMe3 at room temp., stirringovernight; distn. off of solvent, sublimation (74°C/0.1 mbar), then distn. (50°C/0.1 mbar) and crystn. on standing at -30°C for 1 h; elem. anal.;89%
17228-64-7

6-chloro-2-methoxypyridine

107-98-2

1-methoxy-2-propanol

2-methoxy-6-((1-methoxypropan-2-yl)oxy)pyridine

Conditions
ConditionsYield
With C34H47ClNiO3P2; sodium t-butanolate In toluene at 110℃; for 18h; Inert atmosphere; Sealed tube;89%
107-98-2

1-methoxy-2-propanol

34306-42-8

Boc-Abu

(2S)-1-methoxypropan-2-yl 2-((tert-butoxycarbonyl)amino)butanoate

Conditions
ConditionsYield
With dmap; benzotriazol-1-ol; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride; N-ethyl-N,N-diisopropylamine In N,N-dimethyl-formamide at 20℃;88%
107-98-2

1-methoxy-2-propanol

1191102-65-4

ethyl 7-hydroxy-5-[4-(methylsulfonyl)phenoxy]-1H-indole-2-carboxylate

1191103-54-4

ethyl 7-(2-methoxy-1-methylethoxy)-5-[4-(methylsulfonyl)phenoxy]-1H-indole-2-carboxylate

Conditions
ConditionsYield
With tributylphosphine; 1,1'-azodicarbonyl-dipiperidine In tetrahydrofuran at 50℃;87%
107-98-2

1-methoxy-2-propanol

Umemoto's reagent

3,3,3-trifluoro-1-phenylpropyl 1-methoxy-2-propyl ether

Conditions
ConditionsYield
With tris[2-phenylpyridinato-C2,N]iridium(III) In dichloromethane at 20℃; for 2.5h; Schlenk technique; Inert atmosphere; Irradiation; regioselective reaction;87%
107-98-2

1-methoxy-2-propanol

372-09-8

cyanoacetic acid

32804-79-8

1-methoxypropan-2-yl 2-cyanoacetate

Conditions
ConditionsYield
With sulfuric acid In benzene for 2.5h; Fischer esterification; Heating;85%
107-98-2

1-methoxy-2-propanol

89-86-1

4-hydroxysalicylic acid

Conditions
ConditionsYield
With hydrogenchloride; CO2; potassium carbonate In water85%
107-98-2

1-methoxy-2-propanol

77111-77-4

2-chloro-9-(tetrahydro-2H-pyran-2-yl)-9H-purin-6-amine

1050495-05-0

2-([1-methyl-2-(methoxy)ethyl]oxy)-9-(tetrahydro-2H-pyran-2-yl)-9H-purin-6-amine

Conditions
ConditionsYield
With potassium tert-butylate at 80 - 90℃; for 2h;84.7%
  • propylene glycol monomethyl ether

  • Casno:

    107-98-2

    propylene glycol monomethyl ether

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    Min.Order: 1 Kilogram

    FOB Price:  USD $ 10.0-30.0/Kilogram

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  • 1-Methoxy-2-propanol-

  • Casno:

    107-98-2

    1-Methoxy-2-propanol-

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    supplier in China Appearance:colourless liquid Storage:Stored in cool, dry and ventilation place; Away from fire and heat Package:100g/bottle,1kg/bottle,25kg/drum or as per your request Application:1 - methoxy - 2 - propanol are herbicide isopr

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Specification

The CAS registry number of Methoxy propanol is 107-98-2. The IUPAC name is 1-methoxypropan-2-ol. In addition, the molecular formula is C4H10O2. What's more, it is a kind of colourless liquid and incompatible with strong oxidizing agents, acid chlorides, acid anhydrides, water. It is mainly used as a solvent, dispersant and diluent. Besides, it is also used as antifreeze agent for the fuel, extraction solvent.

Physical properties about this chemical are: (1)ACD/LogP: -0.45; (2)ACD/LogD (pH 5.5): -0.45; (3)ACD/LogD (pH 7.4): -0.45; (4)ACD/BCF (pH 5.5): 1; (5)ACD/BCF (pH 7.4): 1; (6)ACD/KOC (pH 5.5): 13.56; (7)ACD/KOC (pH 7.4): 13.56; (8)#H bond acceptors: 2; (9)#H bond donors: 1; (10)#Freely Rotating Bonds: 3; (11)Polar Surface Area: 18.46 Å2; (12)Index of Refraction: 1.397; (13)Molar Refractivity: 23.81 cm3; (14)Molar Volume: 98.8 cm3; (15)Polarizability: 9.44 ×10-24cm3; (16)Surface Tension: 26.9 dyne/cm; (17)Density: 0.912 g/cm3; (18)Flash Point: 33.9 °C; (19)Enthalpy of Vaporization: 41.58 kJ/mol; (20)Boiling Point: 118.5 °C at 760 mmHg; (21)Vapour Pressure: 8.15 mmHg at 25°C.

Preparation of Methoxy propanol: it can be prepared by methyloxirane and methanol. This reaction will need reagent NaOCH3. The yield is about 78%.

Methoxy propanol can be prepared by methyloxirane and methanol

Uses of Methoxy propanol: it can react with oxirane to get 4-methyl-2,5-dioxaheptan-7-ol. This reaction will need reagent BF3*Et2O. The yield is about 53%.

Methoxy propanol can react with oxirane to get 4-methyl-2,5-dioxaheptan-7-ol

When you are using this chemical, please be cautious about it as the following:
This chemical is flammable. During using it, you should avoid contact with skin and eyes. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

You can still convert the following datas into molecular structure:
(1)SMILES: OC(C)COC
(2)InChI: InChI=1/C4H10O2/c1-4(5)3-6-2/h4-5H,3H2,1-2H3
(3)InChIKey: ARXJGSRGQADJSQ-UHFFFAOYAJ

The toxicity data is as follows:

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
dog LD50 intravenous 2gm/kg (2000mg/kg) BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD

BEHAVIORAL: ATAXIA

LUNGS, THORAX, OR RESPIRATION: DYSPNEA
Arzneimittel-Forschung. Drug Research. Vol. 22, Pg. 569, 1972.
dog LD50 oral 5gm/kg (5000mg/kg)   Arzneimittel-Forschung. Drug Research. Vol. 22, Pg. 569, 1972.
guinea pig LCLo inhalation 15000ppm/7H (15000ppm) BEHAVIORAL: SLEEP AMA Archives of Industrial Hygiene and Occupational Medicine. Vol. 9, Pg. 509, 1954.
human TCLo inhalation 3000ppm (3000ppm) SENSE ORGANS AND SPECIAL SENSES: TUMORS: OLFACTION

BEHAVIORAL: GENERAL ANESTHETIC

GASTROINTESTINAL: NAUSEA OR VOMITING
Raw Material Data Handbook, Vol.1: Organic Solvents, 1974. Vol. 1, Pg. 105, 1974.
mouse LD intraperitoneal > 500mg/kg (500mg/kg)   "Summary Tables of Biological Tests," National Research Council Chemical-Biological Coordination Center. Vol. 4, Pg. 110, 1952.
mouse LD50 intravenous 5300mg/kg (5300mg/kg) BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD

BEHAVIORAL: ATAXIA

LUNGS, THORAX, OR RESPIRATION: DYSPNEA
Arzneimittel-Forschung. Drug Research. Vol. 22, Pg. 569, 1972.
mouse LD50 oral 11700mg/kg (11700mg/kg) BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD

BEHAVIORAL: ATAXIA

LUNGS, THORAX, OR RESPIRATION: DYSPNEA
Arzneimittel-Forschung. Drug Research. Vol. 22, Pg. 569, 1972.
rabbit LCLo inhalation 15000ppm/7H (15000ppm)   AMA Archives of Industrial Hygiene and Occupational Medicine. Vol. 9, Pg. 509, 1954.
rabbit LD50 intravenous 1200mg/kg (1200mg/kg)   Arzneimittel-Forschung. Drug Research. Vol. 22, Pg. 569, 1972.
rabbit LD50 oral 5700mg/kg (5700mg/kg)   Arzneimittel-Forschung. Drug Research. Vol. 22, Pg. 569, 1972.
rabbit LD50 skin 13gm/kg (13000mg/kg)   Raw Material Data Handbook, Vol.1: Organic Solvents, 1974. Vol. 1, Pg. 105, 1974.
rabbit LD50 subcutaneous 5gm/kg (5000mg/kg)   Arzneimittel-Forschung. Drug Research. Vol. 22, Pg. 569, 1972.
rat LC50 inhalation 10000ppm/5H (10000ppm)   Raw Material Data Handbook, Vol.1: Organic Solvents, 1974. Vol. 1, Pg. 105, 1974.
rat LD50 intraperitoneal 3720mg/kg (3720mg/kg)   "Patty's Industrial Hygiene and Toxicology," 3rd rev. ed., Clayton, G.D., and F.E. Clayton, eds., New York, John Wiley & Sons, Inc., 1978-82. Vol. 3 originally pub. in 1979; pub. as 2n rev. ed. in 1985.Vol. 2C, Pg. 3977, 1982.
rat LD50 intravenous 4200mg/kg (4200mg/kg) BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD

BEHAVIORAL: ATAXIA

LUNGS, THORAX, OR RESPIRATION: DYSPNEA
Arzneimittel-Forschung. Drug Research. Vol. 22, Pg. 569, 1972.
rat LD50 subcutaneous 7800mg/kg (7800mg/kg) BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD

LUNGS, THORAX, OR RESPIRATION: DYSPNEA

BEHAVIORAL: ATAXIA
Arzneimittel-Forschung. Drug Research. Vol. 22, Pg. 569, 1972.
rat LDLo oral 3739mg/kg (3739mg/kg) SENSE ORGANS AND SPECIAL SENSES: CHROMODACYRORREA: EYE

BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)

BEHAVIORAL: ATAXIA
National Technical Information Service. Vol. OTS0520402,

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