N,N-Diethylhydroxylamine

Base Information

• Chemical Name: N,N-Diethylhydroxylamine
• CAS No.: 3710-84-7
• Molecular Formula: C4H11NO
• Molecular Weight: 89.1374
• Hs Code.: 29280090
• European Community (EC) Number: 223-055-4
• UNII: 314I05EDVH
• DSSTox Substance ID: DTXSID2027543
• Nikkaji Number: J35.165B
• Wikipedia: Diethylhydroxylamine
• Wikidata: Q3334148
• ChEMBL ID: CHEMBL3184786
• Mol file: 3710-84-7.mol

Synonyms:diethylhydroxylamine;N,N-diethylhydroxylamine;N,N-diethylhydroxylamine oxalate;N,N-diethylhydroxylamine oxalate (1:1);N,N-diethylhydroxylamine sulfate (1:1);N,N-diethylhydroxylamine sulfate (2:1)

Chemical Property of N,N-Diethylhydroxylamine

Chemical Property:

• Appearance/Colour: Colorless transparent liquid
• Vapor Pressure: 4 mm Hg ( 0 °C)
• Melting Point: -26--25 °C
• Refractive Index: 1.420
• Boiling Point: 133 °C at 760 mmHg
• PKA: 14.19±0.69(Predicted)
• Flash Point: 45 °C
• PSA: 23.47000
• Density: 0.897 g/cm³
• LogP: 0.71740
• Storage Temp.: Flammables area
• Sensitive.: Hygroscopic
• Water Solubility.: soluble
• XLogP3: 0.5
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 2
• Exact Mass: 89.084063974
• Heavy Atom Count: 6
• Complexity: 26.7

Purity/Quality:

99% ^*data from raw suppliers

N,N-Diethylhydroxylamine ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xn
• Hazard Codes: Xn
• Statements: 10-21-38-40-36/37/38-20/21-53-36/38
• Safety Statements: 36/37-45-36/37/39-26-16

MSDS Files:

Useful:

• Chemical Classes: Nitrogen Compounds -> Hydroxylamines
• Canonical SMILES: CCN(CC)O
• Description: N,N-Diethylhydroxylamine is a colorless and transparent liquid with a boiling point of 125-130 °C and an ammonia odor. It is easily soluble in water, soluble in ethanol, ether, chloroform and benzene.
• Uses: N,N-Diethylhydroxylamine has the following various uses:1.As a vinyl monomer, used in efficient inhibitor agent of conjugate olefins. 2.In liquid or gas phase, if end gather seed is existed,it can be used as inhibitors of end gather. 3.It's a excellent end agent in process of Emulsion-polymerized styrene butadiene rubber. 4.It's a antioxidants of the unsaturated oil and resin. 5.In the environmental protection,it’s good photochemical smoke inhibitors. 6.It's used as corrosion inhibitors in the equipment of the boiler feed water and steam heat exchange. 7.It's used as antioxidant in photography screens potions. Diethylhydroxylamine has been suggested as a stabilizer for color forma-tion for monoalkylphenols and phenolic antioxidants. It has also been reported to stabilize emulsions used in the latex industry and for Spandex rubber, as well as a reducing agent for quinones and a monomer stabilizer or inhibitor. N,N-Diethylhydroxylamine may be employed as a ligand in the preparation of unsymmetric mixed ligand oxadiazoline and/or imine platinum complexes. It may be used in the synthesis of organometallic clusters of mixed hydrazide/hydroxylamide clusters of zinc.

Technology Process of N,N-Diethylhydroxylamine

There total 39 articles about N,N-Diethylhydroxylamine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

diethylamine (109-89-7) → N-ethyl-N-hydroxy-ethanamine (3710-84-7)

Guidance literature:

With 2-hydroxy-N,N,N-trimethyl ethanaminium peroxydisulfate; at 20 ℃; for 1h; chemoselective reaction; Inert atmosphere; Green chemistry;

DOI:10.1055/s-0036-1589089

Reference yield: 54.0%

acetaldehyde (75-07-0,9002-91-9) → N-ethyl-N-hydroxy-ethanamine (3710-84-7)

Guidance literature:

palladium-carbon; In methanol;

Reference yield: 41.0%

C16H20NO2P (102269-06-7) → N-ethyl-N-hydroxy-ethanamine (3710-84-7)

Guidance literature:

With sulfuric acid; In methanol; for 2h; Heating;

DOI:10.1055/s-1985-31359

upstream raw materials:

ethylmagnesium iodide

Nitroethane

diethyl ether

ethyl nitrate

Downstream raw materials:

N,N-diethyl-O-benzoylhydroxylamine

5.5-Diaethyl-1.1-diphenyl-dihydro-1.2.4.5-boradioxazol

C₁₃H₂₀N₂O₂

5.5-Diaethyl-1.1.3-triphenyl-dihydro-1.2.4.5-boradioxazol

Refernces

• 1、 Rauser, Marian,Warzecha, Daniel P.,Niggemann, Meike. "O2-Mediated Oxidation of Aminoboranes through 1,2-N Migration". supporting information. p. 5903 - 5907. Retrieved 2018/05/14.
• 2、 Bai, Xueyin,Liu, Ziwei,Ye, Kaiqi,Wang, Yu,Zhang, Xianlong,Yue, Huijuan,Tian, Ge,Feng, Shouhua. "The oxidation of the alpha-carbon of amines in hydrothermal condition: An alternative synthetic route of compounds containing amide bond". . p. 319 - 321. Retrieved 2014/01/06.