{{(C5H5)2Y(μ-H)}2{(C5H5)2Y(μ-OCH3)}(μ3-H)}(1-)*{Li(THF)4}(1+)

Base Information

• Chemical Name: {{(C5H5)2Y(μ-H)}2{(C5H5)2Y(μ-OCH3)}(μ3-H)}(1-)*{Li(THF)4}(1+)
• CAS No.: 111435-08-6
• Molecular Formula: C₁₆H₃₂LiO₄*C₃₁H₃₆OY₃
• Molecular Weight: 986.713
• Mol file: 111435-08-6.mol

Synonyms:{{(C5H5)2Y(μ-H)}2{(C5H5)2Y(μ-OCH3)}(μ3-H)}(1-)*{Li(THF)4}(1+)

Chemical Property of {{(C5H5)2Y(μ-H)}2{(C5H5)2Y(μ-OCH3)}(μ3-H)}(1-)*{Li(THF)4}(1+)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of {{(C5H5)2Y(μ-H)}2{(C5H5)2Y(μ-OCH3)}(μ3-H)}(1-)*{Li(THF)4}(1+)

There total 1 articles about {{(C5H5)2Y(μ-H)}2{(C5H5)2Y(μ-OCH3)}(μ3-H)}(1-)*{Li(THF)4}(1+) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

methanol (67-56-1) + {{(C5H5)2Y(μ-H)}3(μ3-H)}(1-)*Li(THF)4(1+) (90762-81-5) → {{(C5H5)2Y(μ-H)}2{(C5H5)2Y(μ-OCH3)}(μ3-H)}(1-)*{Li(THF)4}(1+) (111435-08-6) + hydrogen (1333-74-0)

Guidance literature:

In tetrahydrofuran; under inert gas; equiv. amts. of the Y compound in THF and CH3OH combined at -195.8°C; warming to -78°C and stirring for 1.5 h; warming to room temp.; evapn. of the solvent; Y complex pptd. with toluene and centrifugated; chem. anal.;

DOI:10.1021/ja00210a021

Reference yield: 100.0%

methanol (67-56-1) + {{(C5H5)2Y(μ-H)}2{(C5H5)2Y(μ-OCH3)}(μ3-H)}(1-)*{Li(THF)4}(1+) (111435-08-6) → {{(C5H5)2Y(μ-H)}{(C5H5)2Y(OCH3)}2(μ3-H)}(1-)*{Li(THF)4}(1+) (111435-10-0) + hydrogen (1333-74-0)

Guidance literature:

In tetrahydrofuran; under inert gas; equiv. amts of the Y compound in THF and CH3OH combined at -195.8°C; warming to -78°C and stirring for 1.5 h; warming to room temp.; evapn. of the solvent; Y complex pptd. with toluene and centrifugated; chem. anal.;

DOI:10.1021/ja00210a021

upstream raw materials:

methanol

{{(C5H5)2Y(μ-H)}3(μ3-H)}(1-)*Li(THF)4(1+)

Downstream raw materials:

{{(C5H5)2Y(μ-H)}{(C5H5)2Y(OCH3)}2(μ3-H)}(1-)*{Li(THF)4}(1+)

hydrogen