cis-Dichlorobis(triphenylphosphite)platinum(II)

Base Information

• Chemical Name: cis-Dichlorobis(triphenylphosphite)platinum(II)
• CAS No.: 30053-58-8
• Molecular Formula: C36H30 Cl2 O6 P2 Pt
• Molecular Weight: 886.564
• Mol file: 30053-58-8.mol

Synonyms:Platinum,dichlorobis(phosphorous acid)-, hexaphenyl ester, cis- (8CI); Platinum,dichlorobis(triphenyl phosphite-P)-, (SP-4-2)-;cis-Dichlorobis(triphenoxyphosphine)platinum; cis-Dichlorobis(triphenylphosphite)platinum

Chemical Property of cis-Dichlorobis(triphenylphosphite)platinum(II)

Chemical Property:

• Melting Point: ≥300 °C(lit.)
• PSA: 82.56000
• LogP: 12.27710
• Storage Temp.: under inert gas (nitrogen or Argon) at 2-8°C

Purity/Quality:

99% ^*data from raw suppliers

cis-Dichlorobis(triphenylphosphite)platinum(II) 95+% ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-37/39

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of cis-Dichlorobis(triphenylphosphite)platinum(II)

There total 6 articles about cis-Dichlorobis(triphenylphosphite)platinum(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

triphenyl phosphite (101-02-0) + bis(benzonitrile)dichloroplatinum(II) (14873-63-3,15617-19-3,51921-56-3) → cis-[PtCl2(triphenyl phosphite)2] (30053-58-8)

Guidance literature:

In dichloromethane; stirring (10 min); pptn. with pentane, filtration, washing (pentane), drying (vac.);

Reference yield: 98.0%

triphenyl phosphite (101-02-0) + dichloro( 1,5-cyclooctadiene)platinum(ll) (12080-32-9) → cis-[PtCl2(triphenyl phosphite)2] (30053-58-8)

Guidance literature:

In benzene; (N2), soln. of Pt complex in benzene treated with 2 equiv. of phosphane,stirred at room temp. for 1 h; filtered, washed (benzene);

DOI:10.1002/ejic.200900834

Reference yield: 14.0%

triphenyl phosphite (101-02-0) + platinum(II) chloride (10025-65-7) → cis-[PtCl2(triphenyl phosphite)2] (30053-58-8)

Guidance literature:

In melt; addn. of PtCl2 to melt of ligand (stirring, 30 min); cooling to room temp., dissolution in CHCl3, filtration (Celite), pptn. on Et2O addn., sepn. (centrifugation);

DOI:10.1016/S0020-1693(00)80914-7

upstream raw materials:

triphenyl phosphite

bis(benzonitrile)dichloroplatinum(II)

platinum(II) chloride

dichloro( 1,5-cyclooctadiene)platinum(ll)

Downstream raw materials:

platinum

PtCl(SnCl₃)(P(OC₆H₅)3)2

Pt(SnCl₃)2(P(OC₆H₅)3)2

Pt(SnCl₃)3(P(OC₆H₅)3)2^(1-)

Refernces

• 1、 Kamon, Hitomi,Aoki, Yutaro,Nakata, Norio,Ishii, Akihiko. "Characterization and phenylacetylene-assisted cyclometalation of an isolable hydrido-selenolato PtII complex having phosphite ligands, cis-[PtH(SeTrip){P(OPh)3}2]#". . p. 274 - 282. Retrieved 2014/03/21.
• 2、 Kajiyama, Kazumasa,Sato, Issei,Yamashita, Satoru,Miyamoto, Takeshi K.. "Syntheses and characterization of novel bis(phosphoranido)platinum(II) complexes: Reactions of lithium bis(naphth-l,8-diyl-8-oxy)phosphoranide with cis-PtCl2(PRs)2 (R = OPh, OMe, Me)". . p. 5516 - 5521. Retrieved 2010/06/15.