1,3,5-Tri-O-benzoyl-2-C-methyl-D-arabinofuranose

Base Information

Chemical Name:1,3,5-Tri-O-benzoyl-2-C-methyl-D-arabinofuranose
CAS No.:16434-48-3
Molecular Formula:C27H24 O8
Molecular Weight:476.483
Hs Code.:
DSSTox Substance ID:DTXSID30705354
Mol file:16434-48-3.mol

Synonyms:DTXSID30705354;1,3,5-Tri-O-benzoyl-2-C-methyl-D-arabinofuranose

Suppliers and Price of 1,3,5-Tri-O-benzoyl-2-C-methyl-D-arabinofuranose

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

American Custom Chemicals Corporation
2-C-METHYL-1,3,5-TRI-O-BENZOYL-ALPHA-D-RIBOFURANOSIDE 95.00%
5MG
$ 498.76

Total 27 raw suppliers

Chemical Property of 1,3,5-Tri-O-benzoyl-2-C-methyl-D-arabinofuranose

Chemical Property:

Boiling Point:627.0±55.0 °C(Predicted)
PKA:12.42±0.70(Predicted)
PSA：108.36000
Density:1.35±0.1 g/cm3(Predicted)
LogP:3.40190
XLogP3:4.4
Hydrogen Bond Donor Count:1
Hydrogen Bond Acceptor Count:8
Rotatable Bond Count:10
Exact Mass:476.14711772
Heavy Atom Count:35
Complexity:736

Purity/Quality:

98%,99%, ^*data from raw suppliers

2-C-METHYL-1,3,5-TRI-O-BENZOYL-ALPHA-D-RIBOFURANOSIDE 95.00% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC1(C(C(OC1OC(=O)C2=CC=CC=C2)COC(=O)C3=CC=CC=C3)OC(=O)C4=CC=CC=C4)O
Isomeric SMILES:C[C@@]1([C@@H]([C@H](OC1OC(=O)C2=CC=CC=C2)COC(=O)C3=CC=CC=C3)OC(=O)C4=CC=CC=C4)O

Technology Process of 1,3,5-Tri-O-benzoyl-2-C-methyl-D-arabinofuranose

There total 2 articles about 1,3,5-Tri-O-benzoyl-2-C-methyl-D-arabinofuranose which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 75-16-1
methylmagnesium bromide

: 157037-56-4
1,3,5-tri-O-benzoyl-2-oxo-α-D-erythro-pentofuranose

: 16434-48-3
1,3,5-tri-O-benzoyl-2-C-methyl-α-D-ribofuranose

: 30361-17-2
2,3,5-tri-O-benzoyl-2-C-methyl-α/β-D-ribofuranose

Guidance literature:: With titanium tetrachloride; Multistep reaction; 1.) ether, -78 deg.C; 2.) ether, 4 h, -30 - -40 deg.C;
DOI:10.1016/0040-4039(95)01635-U

Reference yield:

: 2747-38-8
methyltrichlorotitanium

: 157037-56-4
1,3,5-tri-O-benzoyl-2-oxo-α-D-erythro-pentofuranose

: 16434-48-3
1,3,5-tri-O-benzoyl-2-C-methyl-α-D-ribofuranose

: 30361-17-2
2,3,5-tri-O-benzoyl-2-C-methyl-α/β-D-ribofuranose

Guidance literature:: Title compound not separated from byproducts;
DOI:10.1080/07328319708006205

Reference yield:

: 16434-48-3
1,3,5-tri-O-benzoyl-2-C-methyl-α-D-ribofuranose

: 30361-17-2
2,3,5-tri-O-benzoyl-2-C-methyl-α/β-D-ribofuranose

: 98-88-4
benzoyl chloride

: 15397-15-6
1,2,3,5-tetra-O-benzoyl-2-C-methyl-β-D-ribofuranose

: (2R,3R,4R,5R)-5-(benzoyloxymethyl)-3-methyltetrahydrofuran-2,3,4-triyl tribenzoate

Guidance literature:: With dmap; triethylamine; In dichloromethane; for 3h; Yields of byproduct given; Ambient temperature;
DOI:10.1021/jo961893+