Technology Process of (μ,η2-PhCO)(μ-EtS)Fe2(CO)6
There total 4 articles about (μ,η2-PhCO)(μ-EtS)Fe2(CO)6 which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
With
triethylamine;
Fe3(CO)12 reacted with C2H5SH and Et3N, then triethylammonium salt reacted with C6H5COCl;
- Guidance literature:
-
With
triethylamine;
In
tetrahydrofuran;
addn. of thiol and Et3N to Fe3(CO)12 soln. (equim. amts., room temp., N2-atmosphere), addn. of Hg-compd., stirring (3 h); chromy. (SiO2, pentane);
- Guidance literature:
-
In
tetrahydrofuran;
reaction carried out under N2; C2H5SH and (C2H5)3N added to soln. of Fe3(CO)12 in THF, stirred (15 min.),benzoylchloride added, stirred (20h), dark red soln. with white ppt., filtered, solvent removed, red oil dissolved in pentane, extd., filtered; filtration chromy. (silicic acid/pentane); ratio of isomers 2.3:1 (e-Et/a-Et), yield of isomer mixt. 83%;
