Mercury, bromophenyl-

Base Information

• Chemical Name: Mercury, bromophenyl-
• CAS No.: 1192-89-8
• Molecular Formula: C6H5 Br Hg
• Molecular Weight: 357.6
• Hs Code.: 2931900090
• European Community (EC) Number: 214-760-8
• NSC Number: 126136
• DSSTox Substance ID: DTXSID6074465
• Wikidata: Q27281050
• Mol file: 1192-89-8.mol

Synonyms:MERCURY, BROMOPHENYL-;1192-89-8;Phenylmercuric bromide;Phenylmercury bromide;Bromophenylmercury;bromo(phenyl)mercury;Fenylmerkuribromid;PHENYL MERCURIC BROMIDE;Fenylmerkuribromid [Czech];(Bromomercuri)benzene;EINECS 214-760-8;NSC 126136;BRN 3661320;UNII-J27OJX258B;Phentlmercuric bromide;C6H5BrHg;Phenylmercury(II) bromide;C6-H5-Br-Hg;PHENYLMERCURICBROMIDE;WLN: E-HG-R;SCHEMBL8845549;DTXSID6074465;NSC126136;AKOS024430453;LS-89670;FT-0633448;Q27281050

Chemical Property of Mercury, bromophenyl-

Chemical Property:

• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 0.00000
• Density: g/cm³
• LogP: 1.70430
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 357.92811
• Heavy Atom Count: 8
• Complexity: 59.5

Purity/Quality:

98%,99%, ^*data from raw suppliers

(BROMOMERCURI)BENZENE AldrichCPR ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: C1=CC=C(C=C1)[Hg]Br

Technology Process of Mercury, bromophenyl-

There total 35 articles about Mercury, bromophenyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

diphenyliodonium bromide (1483-73-4) + mercury → iodobenzene (591-50-4) + biphenyl (92-52-4,1594-86-1) + mercury(I) bromide + bromo(phenyl)mercury (1192-89-8) + benzene (71-43-2,26181-88-4,54682-86-9,13967-78-7,174973-66-1)

Guidance literature:

In acetonitrile; byproducts: C6H5Br; at different temp. between 20-70°C; UV; yields for 45°C; Kinetics;

DOI:10.1007/BF00963679

Reference yield: 96.5%

phenylmercury trichloroacetate (14076-29-0) + sodium bromide (7647-15-6) → bromo(phenyl)mercury (1192-89-8)

Guidance literature:

In methanol; addn. of PhHgOCOCCl3 soln. to soln. of NaBr with stirring, pptn.; ppt. filtered, washed (water, methanol);

Reference yield: 94.0%

phenyltrifluorosilane (368-47-8) → bromo(phenyl)mercury (1192-89-8)

Guidance literature:

With mercury dibromide; In tetrahydrofuran; byproducts: BrSiF3; addn. of trifluorophenylsilane to a suspn. of HgBr2 in dry THF, reacting at 65°C for 1 h, pptn.;

DOI:10.1016/0022-328X(88)89077-6

upstream raw materials:

mercury(II) cyanide

aniline

t-butyl bromide

toluene

Downstream raw materials:

dibenzylmercury(II)

diphenyl sulfide

(μ,η2-PhCO)(μ-EtS)Fe2(CO)6

(μ,η2-PhCO)(μ-Me3CS)Fe2(CO)6

Refernces

• 1、 Rasuwajew,Oldekop. "-". . . Retrieved 1950.
• 2、 -. "Diphenylcyclopropyl analogs". . . Retrieved 2008/06/13.
• 3、 -. "Diphenylcyclopropyl analogs". . . Retrieved 2008/06/13.