TpOs(NDPh)Cl₂

Base Information

Chemical Name:TpOs(NDPh)Cl₂
CAS No.:604783-60-0
Molecular Formula:C₁₅H₁₆BCl₂N₇Os
Molecular Weight:567.248
Hs Code.:

Synonyms:TpOs(NDPh)Cl₂

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Chemical Property of TpOs(NDPh)Cl₂

Chemical Property:

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Technology Process of TpOs(NDPh)Cl₂

There total 7 articles about TpOs(NDPh)Cl₂ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

: dichloro(hydrotris(1-pyrazolyl)borate)(nitrido)osmium(IV)

: 7789-20-0
water-d2

: 100-58-3
phenylmagnesium bromide

: 604783-60-0
TpOs(NDPh)Cl₂

Guidance literature:: In tetrahydrofuran; diethyl ether; under inert atm.; soln. of C6H5MgBr in Et2O added dropwise over 1.5 h tostirred soln. of Os complex in THF at -78°C; stirred for 1 h; wa rmed; quenching with D2O; solvent removed (vac.); column chromd. on silica pretreated with D2O in air (96% CH2Cl2/4% acetone); recrystd. (CH2Cl2/pentane);
DOI:10.1021/ja036328k

Reference yield:

: dichloro(hydrotris(1-pyrazolyl)borate)(nitrido)osmium(IV)

: 100-59-4
phenylmagnesium chloride

: 7789-20-0
water-d2

: 604783-60-0
TpOs(NDPh)Cl₂

Guidance literature:: In diethyl ether; addn. of 1 equiv. of PhMgCl to an ether soln. of Os-contg. compd. at -78°C; (1)H NMR studies;
DOI:10.1021/ja0028424

Reference yield:

: TpOs(NHPh)Cl₂

: 604783-60-0
TpOs(NDPh)Cl₂

Guidance literature:: Multi-step reaction with 4 steps

1: chloroform-d1

2: chloroform-d1

3: tetrahydrofuran; diethyl ether

4: benzene-d6

In tetrahydrofuran; diethyl ether; chloroform-d1; benzene-d6;
DOI:10.1021/ic001177x