4-(5-(4-(N-phenyl-N-(4-hydroxyphenyl)amino)phenyl)-thien-2-yl)-7-(4-(di-(4-methoxyphenyl)-amino)-phenyl)-2,1,3-benzothiadiazole

Base Information

Chemical Name:4-(5-(4-(N-phenyl-N-(4-hydroxyphenyl)amino)phenyl)-thien-2-yl)-7-(4-(di-(4-methoxyphenyl)-amino)-phenyl)-2,1,3-benzothiadiazole
CAS No.:1253294-07-3
Molecular Formula:C₄₈H₃₆N₄O₃S₂
Molecular Weight:780.971
Hs Code.:

Synonyms:4-(5-(4-(N-phenyl-N-(4-hydroxyphenyl)amino)phenyl)-thien-2-yl)-7-(4-(di-(4-methoxyphenyl)-amino)-phenyl)-2,1,3-benzothiadiazole

Suppliers and Price of 4-(5-(4-(N-phenyl-N-(4-hydroxyphenyl)amino)phenyl)-thien-2-yl)-7-(4-(di-(4-methoxyphenyl)-amino)-phenyl)-2,1,3-benzothiadiazole

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 4-(5-(4-(N-phenyl-N-(4-hydroxyphenyl)amino)phenyl)-thien-2-yl)-7-(4-(di-(4-methoxyphenyl)-amino)-phenyl)-2,1,3-benzothiadiazole

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 4-(5-(4-(N-phenyl-N-(4-hydroxyphenyl)amino)phenyl)-thien-2-yl)-7-(4-(di-(4-methoxyphenyl)-amino)-phenyl)-2,1,3-benzothiadiazole

There total 7 articles about 4-(5-(4-(N-phenyl-N-(4-hydroxyphenyl)amino)phenyl)-thien-2-yl)-7-(4-(di-(4-methoxyphenyl)-amino)-phenyl)-2,1,3-benzothiadiazole which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.3%

: 1253294-06-2
4-(5-(4-(N-phenyl-N-(4-(tert-butyldimethylsilyloxy)phenyl)amino)phenyl)-thien-2-yl)-7-(4-(di-(4-methoxyphenyl)-amino)phenyl)-2,1,3-benzothiadiazole

: 1253294-07-3
4-(5-(4-(N-phenyl-N-(4-hydroxyphenyl)amino)phenyl)-thien-2-yl)-7-(4-(di-(4-methoxyphenyl)-amino)-phenyl)-2,1,3-benzothiadiazole

Guidance literature:: With hydrogenchloride; In tetrahydrofuran; water;
DOI:10.1002/adfm.201000840

Reference yield:

: 194416-45-0
4-bromo-N,N-bis-(4-methoxyphenyl)aniline

: 1253294-07-3
4-(5-(4-(N-phenyl-N-(4-hydroxyphenyl)amino)phenyl)-thien-2-yl)-7-(4-(di-(4-methoxyphenyl)-amino)-phenyl)-2,1,3-benzothiadiazole

Guidance literature:: Multi-step reaction with 4 steps

1: dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH₂Cl₂; potassium acetate / N,N-dimethyl-formamide / 12 h / 80 °C

2: tetrakis(triphenylphosphine) palladium⁽⁰⁾; Aliquat 336; potassium carbonate / toluene / 12 h / 90 °C / Darkness

3: tetrakis(triphenylphosphine) palladium⁽⁰⁾ / toluene / 24 h / 100 °C / Darkness

4: hydrogenchloride / tetrahydrofuran; water

With hydrogenchloride; tetrakis(triphenylphosphine) palladium⁽⁰⁾; dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH₂Cl₂; potassium acetate; Aliquat 336; potassium carbonate; In tetrahydrofuran; water; N,N-dimethyl-formamide; toluene; 2: Suzuki coupling / 3: Stille coupling;
DOI:10.1002/adfm.201000840

Reference yield:

: 875667-84-8
4-methoxy-N-(4-methoxyphenyl)-N-[4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]benzenamine

: 1253294-07-3
4-(5-(4-(N-phenyl-N-(4-hydroxyphenyl)amino)phenyl)-thien-2-yl)-7-(4-(di-(4-methoxyphenyl)-amino)-phenyl)-2,1,3-benzothiadiazole

Guidance literature:: Multi-step reaction with 3 steps

1: tetrakis(triphenylphosphine) palladium⁽⁰⁾; Aliquat 336; potassium carbonate / toluene / 12 h / 90 °C / Darkness

2: tetrakis(triphenylphosphine) palladium⁽⁰⁾ / toluene / 24 h / 100 °C / Darkness

3: hydrogenchloride / tetrahydrofuran; water

With hydrogenchloride; tetrakis(triphenylphosphine) palladium⁽⁰⁾; Aliquat 336; potassium carbonate; In tetrahydrofuran; water; toluene; 1: Suzuki coupling / 2: Stille coupling;
DOI:10.1002/adfm.201000840