4-(5-(4-(N-phenyl-N-(4-(tert-butyldimethylsilyloxy)phenyl)amino)phenyl)-thien-2-yl)-7-(4-(di-(4-methoxyphenyl)-amino)phenyl)-2,1,3-benzothiadiazole

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Chemical Name:4-(5-(4-(N-phenyl-N-(4-(tert-butyldimethylsilyloxy)phenyl)amino)phenyl)-thien-2-yl)-7-(4-(di-(4-methoxyphenyl)-amino)phenyl)-2,1,3-benzothiadiazole
CAS No.:1253294-06-2
Molecular Formula:C₅₄H₅₀N₄O₃S₂Si
Molecular Weight:895.233
Hs Code.:

Synonyms:4-(5-(4-(N-phenyl-N-(4-(tert-butyldimethylsilyloxy)phenyl)amino)phenyl)-thien-2-yl)-7-(4-(di-(4-methoxyphenyl)-amino)phenyl)-2,1,3-benzothiadiazole

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Chemical Property of 4-(5-(4-(N-phenyl-N-(4-(tert-butyldimethylsilyloxy)phenyl)amino)phenyl)-thien-2-yl)-7-(4-(di-(4-methoxyphenyl)-amino)phenyl)-2,1,3-benzothiadiazole

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Technology Process of 4-(5-(4-(N-phenyl-N-(4-(tert-butyldimethylsilyloxy)phenyl)amino)phenyl)-thien-2-yl)-7-(4-(di-(4-methoxyphenyl)-amino)phenyl)-2,1,3-benzothiadiazole

There total 5 articles about 4-(5-(4-(N-phenyl-N-(4-(tert-butyldimethylsilyloxy)phenyl)amino)phenyl)-thien-2-yl)-7-(4-(di-(4-methoxyphenyl)-amino)phenyl)-2,1,3-benzothiadiazole which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.7%

: 1253293-99-0
4-(7-bromobenzo[c] [1,2,5]thiadiazol-4-yl)-N,N-bis(4-methoxyphenyl)aniline

: 1253294-01-7
tributyl (5-(4-(N-phenyl-N-(4-(tert-butyldimethylsilyloxy)phenyl)amino)phenyl)-thien-2-yl)stannane

: 1253294-06-2
4-(5-(4-(N-phenyl-N-(4-(tert-butyldimethylsilyloxy)phenyl)amino)phenyl)-thien-2-yl)-7-(4-(di-(4-methoxyphenyl)-amino)phenyl)-2,1,3-benzothiadiazole

Guidance literature:: With tetrakis(triphenylphosphine) palladium⁽⁰⁾; In toluene; at 100 ℃; for 24h; Darkness;
DOI:10.1002/adfm.201000840

Reference yield:

: 194416-45-0
4-bromo-N,N-bis-(4-methoxyphenyl)aniline

: 1253294-06-2
4-(5-(4-(N-phenyl-N-(4-(tert-butyldimethylsilyloxy)phenyl)amino)phenyl)-thien-2-yl)-7-(4-(di-(4-methoxyphenyl)-amino)phenyl)-2,1,3-benzothiadiazole

Guidance literature:: Multi-step reaction with 3 steps

1: dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH₂Cl₂; potassium acetate / N,N-dimethyl-formamide / 12 h / 80 °C

2: tetrakis(triphenylphosphine) palladium⁽⁰⁾; Aliquat 336; potassium carbonate / toluene / 12 h / 90 °C / Darkness

3: tetrakis(triphenylphosphine) palladium⁽⁰⁾ / toluene / 24 h / 100 °C / Darkness

With tetrakis(triphenylphosphine) palladium⁽⁰⁾; dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH₂Cl₂; potassium acetate; Aliquat 336; potassium carbonate; In N,N-dimethyl-formamide; toluene; 2: Suzuki coupling / 3: Stille coupling;
DOI:10.1002/adfm.201000840

Reference yield:

: 875667-84-8
4-methoxy-N-(4-methoxyphenyl)-N-[4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]benzenamine

: 1253294-06-2
4-(5-(4-(N-phenyl-N-(4-(tert-butyldimethylsilyloxy)phenyl)amino)phenyl)-thien-2-yl)-7-(4-(di-(4-methoxyphenyl)-amino)phenyl)-2,1,3-benzothiadiazole

Guidance literature:: Multi-step reaction with 2 steps

1: tetrakis(triphenylphosphine) palladium⁽⁰⁾; Aliquat 336; potassium carbonate / toluene / 12 h / 90 °C / Darkness

2: tetrakis(triphenylphosphine) palladium⁽⁰⁾ / toluene / 24 h / 100 °C / Darkness

With tetrakis(triphenylphosphine) palladium⁽⁰⁾; Aliquat 336; potassium carbonate; In toluene; 1: Suzuki coupling / 2: Stille coupling;
DOI:10.1002/adfm.201000840