10-((1E,3E)-4-(2-(4-bromophenyl)-2H-tetrazol-5-yl)buta-1,3-dien-1-yl)-10H-phenothiazine

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Chemical Name:10-((1E,3E)-4-(2-(4-bromophenyl)-2H-tetrazol-5-yl)buta-1,3-dien-1-yl)-10H-phenothiazine
CAS No.:1256974-08-9
Molecular Formula:C₂₃H₁₆BrN₅S
Molecular Weight:474.384
Hs Code.:

Synonyms:10-((1E,3E)-4-(2-(4-bromophenyl)-2H-tetrazol-5-yl)buta-1,3-dien-1-yl)-10H-phenothiazine

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Chemical Property of 10-((1E,3E)-4-(2-(4-bromophenyl)-2H-tetrazol-5-yl)buta-1,3-dien-1-yl)-10H-phenothiazine

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Technology Process of 10-((1E,3E)-4-(2-(4-bromophenyl)-2H-tetrazol-5-yl)buta-1,3-dien-1-yl)-10H-phenothiazine

There total 1 articles about 10-((1E,3E)-4-(2-(4-bromophenyl)-2H-tetrazol-5-yl)buta-1,3-dien-1-yl)-10H-phenothiazine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

: 92-84-2
10H-phenothiazine

: 3-(4-bromophenyl)-tetrazolo[1,5-a]pyridin-4-ium tetrafluoroborate

: 1256974-08-9
10-((1E,3E)-4-(2-(4-bromophenyl)-2H-tetrazol-5-yl)buta-1,3-dien-1-yl)-10H-phenothiazine

Guidance literature:: With sodium hydride; In tetrahydrofuran; at 20 ℃; for 48h;
DOI:10.1016/j.jorganchem.2010.08.049

Reference yield: 33.0%

: 1256974-08-9
10-((1E,3E)-4-(2-(4-bromophenyl)-2H-tetrazol-5-yl)buta-1,3-dien-1-yl)-10H-phenothiazine

: 6-((10H-phenothiazin-10-yl)methyl)-2-(4-bromophenyl)-5,6,7,8-tetrahydro-2H-tetrazolo[5,1-f][1,2]azaborinin-4-ium-5-uide

Guidance literature:: With borane-dimethyl sulfide complex; In tetrahydrofuran; at 0 - 20 ℃; for 3h; Inert atmosphere;
DOI:10.1016/j.jorganchem.2010.08.049

Reference yield: 33.0%

: 1256974-08-9
10-((1E,3E)-4-(2-(4-bromophenyl)-2H-tetrazol-5-yl)buta-1,3-dien-1-yl)-10H-phenothiazine

: 13292-87-0
dimethyl sulfide borane

: 1256974-12-5
6-((10H-phenothiazin-10-yl)methyl)-2-(4-bromophenyl)-5,6,7,8-tetrahydro-2H-tetrazolo[5,1-f][1,2]azaborinin-4-ium-5-uide

Guidance literature:: In tetrahydrofuran; (inert atm.); addn. of borane deriv. to suspn. of tetrazole deriv. in abs. THF, stirring at 0°C to room temp. for 3 h; addn. of water at 0°C, addn. of sodium carbonate soln., extn. (CH2Cl2), drying over Na2SO4, filtration, evapn. in vac. at room temp., chromy. (silica gel, hexane/CH2Cl2 (2:1)), recrystn. (hexane/diethyl ether), elem. anal.;
DOI:10.1016/j.jorganchem.2010.08.049