6-((10H-phenothiazin-10-yl)methyl)-2-(4-bromophenyl)-5,6,7,8-tetrahydro-2H-tetrazolo[5,1-f][1,2]azaborinin-4-ium-5-uide

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Chemical Name:6-((10H-phenothiazin-10-yl)methyl)-2-(4-bromophenyl)-5,6,7,8-tetrahydro-2H-tetrazolo[5,1-f][1,2]azaborinin-4-ium-5-uide
CAS No.:1256974-12-5
Molecular Formula:C₂₃H₂₁BBrN₅S
Molecular Weight:490.234
Hs Code.:

Synonyms:6-((10H-phenothiazin-10-yl)methyl)-2-(4-bromophenyl)-5,6,7,8-tetrahydro-2H-tetrazolo[5,1-f][1,2]azaborinin-4-ium-5-uide

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Chemical Property of 6-((10H-phenothiazin-10-yl)methyl)-2-(4-bromophenyl)-5,6,7,8-tetrahydro-2H-tetrazolo[5,1-f][1,2]azaborinin-4-ium-5-uide

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Technology Process of 6-((10H-phenothiazin-10-yl)methyl)-2-(4-bromophenyl)-5,6,7,8-tetrahydro-2H-tetrazolo[5,1-f][1,2]azaborinin-4-ium-5-uide

There total 3 articles about 6-((10H-phenothiazin-10-yl)methyl)-2-(4-bromophenyl)-5,6,7,8-tetrahydro-2H-tetrazolo[5,1-f][1,2]azaborinin-4-ium-5-uide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 33.0%

: 1256974-08-9
10-((1E,3E)-4-(2-(4-bromophenyl)-2H-tetrazol-5-yl)buta-1,3-dien-1-yl)-10H-phenothiazine

: 13292-87-0
dimethyl sulfide borane

: 1256974-12-5
6-((10H-phenothiazin-10-yl)methyl)-2-(4-bromophenyl)-5,6,7,8-tetrahydro-2H-tetrazolo[5,1-f][1,2]azaborinin-4-ium-5-uide

Guidance literature:: In tetrahydrofuran; (inert atm.); addn. of borane deriv. to suspn. of tetrazole deriv. in abs. THF, stirring at 0°C to room temp. for 3 h; addn. of water at 0°C, addn. of sodium carbonate soln., extn. (CH2Cl2), drying over Na2SO4, filtration, evapn. in vac. at room temp., chromy. (silica gel, hexane/CH2Cl2 (2:1)), recrystn. (hexane/diethyl ether), elem. anal.;
DOI:10.1016/j.jorganchem.2010.08.049

Reference yield:

: 1387626-36-9
10-((1E,3Z)-4-(2-(4-bromophenyl)-2H-tetrazol-5-yl)buta-1,3-dien-1-yl)-10H-phenothiazine

: 1256974-12-5
6-((10H-phenothiazin-10-yl)methyl)-2-(4-bromophenyl)-5,6,7,8-tetrahydro-2H-tetrazolo[5,1-f][1,2]azaborinin-4-ium-5-uide

Guidance literature:: With dimethylsulfide borane complex; In tetrahydrofuran; at 0 - 20 ℃; for 24h; Inert atmosphere;
DOI:10.1016/j.bmc.2012.05.065

Reference yield:

: 92-84-2
10H-phenothiazine

: 1256974-12-5
6-((10H-phenothiazin-10-yl)methyl)-2-(4-bromophenyl)-5,6,7,8-tetrahydro-2H-tetrazolo[5,1-f][1,2]azaborinin-4-ium-5-uide

Guidance literature:: Multi-step reaction with 2 steps

1: sodium hydride / tetrahydrofuran; mineral oil / 48.33 h

2: dimethylsulfide borane complex / tetrahydrofuran / 24 h / 0 - 20 °C / Inert atmosphere

With dimethylsulfide borane complex; sodium hydride; In tetrahydrofuran; mineral oil;
DOI:10.1016/j.bmc.2012.05.065