(Z)-2-(benzyloxy)-1-(4'-methyl-2',6,-di-tert-butylphenoxy)-1-((trimethylsilyl)oxy)propene

Base Information

Chemical Name:(Z)-2-(benzyloxy)-1-(4'-methyl-2',6,-di-tert-butylphenoxy)-1-((trimethylsilyl)oxy)propene
CAS No.:92817-67-9
Molecular Formula:C₂₈H₄₂O₃Si
Molecular Weight:454.725
Hs Code.:

Synonyms:(Z)-2-(benzyloxy)-1-(4'-methyl-2',6,-di-tert-butylphenoxy)-1-((trimethylsilyl)oxy)propene

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (Z)-2-(benzyloxy)-1-(4'-methyl-2',6,-di-tert-butylphenoxy)-1-((trimethylsilyl)oxy)propene

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Technology Process of (Z)-2-(benzyloxy)-1-(4'-methyl-2',6,-di-tert-butylphenoxy)-1-((trimethylsilyl)oxy)propene

There total 3 articles about (Z)-2-(benzyloxy)-1-(4'-methyl-2',6,-di-tert-butylphenoxy)-1-((trimethylsilyl)oxy)propene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 73.0%

: 75-77-4
chloro-trimethyl-silane

: 78957-59-2
2',6'-di-tert-butyl-4'-methylphenyl (RS)-2-(benzyloxy)propanoate

: 92817-67-9
(Z)-2-(benzyloxy)-1-(4'-methyl-2',6,-di-tert-butylphenoxy)-1-((trimethylsilyl)oxy)propene

Guidance literature:: With lithium diisopropyl amide; In tetrahydrofuran; 1.) -78 deg C, 1 h; 2.) r.t., 2 h;
DOI:10.1021/ja00338a027

Reference yield:

: 128-37-0
2,6-di-tert-butyl-4-methyl-phenol

: 92817-67-9
(Z)-2-(benzyloxy)-1-(4'-methyl-2',6,-di-tert-butylphenoxy)-1-((trimethylsilyl)oxy)propene

Guidance literature:: Multi-step reaction with 2 steps

1: 84 percent / 1.5 M n-BuLi / tetrahydrofuran; hexane / 1.) -78 deg C, 3 h; 2.) r.t., overnight

2: 73 percent / LDA / tetrahydrofuran / 1.) -78 deg C, 1 h; 2.) r.t., 2 h

With n-butyllithium; lithium diisopropyl amide; In tetrahydrofuran; hexane;
DOI:10.1021/ja00338a027

Reference yield:

: 56972-68-0
2-benzyloxy-propionyl chloride

: 92817-67-9
(Z)-2-(benzyloxy)-1-(4'-methyl-2',6,-di-tert-butylphenoxy)-1-((trimethylsilyl)oxy)propene

Guidance literature:: Multi-step reaction with 2 steps

1: 84 percent / 1.5 M n-BuLi / tetrahydrofuran; hexane / 1.) -78 deg C, 3 h; 2.) r.t., overnight

2: 73 percent / LDA / tetrahydrofuran / 1.) -78 deg C, 1 h; 2.) r.t., 2 h

With n-butyllithium; lithium diisopropyl amide; In tetrahydrofuran; hexane;
DOI:10.1021/ja00338a027