4-Methylphenyl dihydrogen borate

Base Information

Chemical Name:4-Methylphenyl dihydrogen borate
CAS No.:274251-50-2
Molecular Formula:C₇H₉BO₃
Molecular Weight:151.958
Hs Code.:
DSSTox Substance ID:DTXSID10597597
Wikidata:Q82493208

Synonyms:4-tolylboric acid;274251-50-2;4-Methylphenyl dihydrogen borate;4-methylphenyl boric acid;4-methyl-phenyl-boric acid;SCHEMBL350471;DTXSID10597597;DQVXWCCLFKMJTQ-UHFFFAOYSA-N

Suppliers and Price of 4-Methylphenyl dihydrogen borate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

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Chemical Property of 4-Methylphenyl dihydrogen borate

Chemical Property:

Hydrogen Bond Donor Count:2
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:2
Exact Mass:152.0644743
Heavy Atom Count:11
Complexity:110

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:B(O)(O)OC1=CC=C(C=C1)C

Technology Process of 4-Methylphenyl dihydrogen borate

There total 3 articles about 4-Methylphenyl dihydrogen borate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 772-80-5
4-methylphenyl chlorosulfate

: 5720-07-0
4-methoxyphenylboronic acid

: 98-68-0
4-methoxy-phenyl-sulphonyl chloride

: 274251-50-2
p-tolylboric acid

Guidance literature:: With C₄₃H₄₃NO₃PPdS; sodium carbonate; In [⁽²⁾H₆]acetone; at 60 ℃; for 6h;
DOI:10.1021/ja405949a

Reference yield:

: 5419-55-6
Triisopropyl borate

: 106-38-7
para-bromotoluene

: 274251-50-2
p-tolylboric acid

Guidance literature:: With hydrogenchloride; n-butyllithium; In tetrahydrofuran; hexane;

Reference yield:

: 106-44-5
p-cresol

: 274251-50-2
p-tolylboric acid

Guidance literature:: Multi-step reaction with 2 steps

1: pyridine; sulfuryl dichloride / diethyl ether / 2 h / -78 - 20 °C / Inert atmosphere

2: sodium carbonate; C₄₃H₄₃NO₃PPdS / [⁽²⁾H₆]acetone / 6 h / 60 °C

With pyridine; sulfuryl dichloride; C₄₃H₄₃NO₃PPdS; sodium carbonate; In diethyl ether; [⁽²⁾H₆]acetone;
DOI:10.1021/ja405949a