2-[(3,4-bisdecyloxy)phenyl]methoxy-[1,1'-biphenyl]-6,3'-dicarboxylic acid, diethyl ester

Base Information

Chemical Name:2-[(3,4-bisdecyloxy)phenyl]methoxy-[1,1'-biphenyl]-6,3'-dicarboxylic acid, diethyl ester
CAS No.:163117-60-0
Molecular Formula:C₄₅H₆₄O₇
Molecular Weight:716.999
Hs Code.:

Synonyms:2-[(3,4-bisdecyloxy)phenyl]methoxy-[1,1'-biphenyl]-6,3'-dicarboxylic acid, diethyl ester

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Chemical Property of 2-[(3,4-bisdecyloxy)phenyl]methoxy-[1,1'-biphenyl]-6,3'-dicarboxylic acid, diethyl ester

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Technology Process of 2-[(3,4-bisdecyloxy)phenyl]methoxy-[1,1'-biphenyl]-6,3'-dicarboxylic acid, diethyl ester

There total 7 articles about 2-[(3,4-bisdecyloxy)phenyl]methoxy-[1,1'-biphenyl]-6,3'-dicarboxylic acid, diethyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 44.0%

: 163117-35-9
2-hydroxy-3'-carboethoxy-[1,1'-biphenyl]-6-carboxylic acid, ethyl ester

: 163117-49-5
3,4-didecyloxybenzyl alcohol

: 163117-60-0
2-[(3,4-bisdecyloxy)phenyl]methoxy-[1,1'-biphenyl]-6,3'-dicarboxylic acid, diethyl ester

Guidance literature:: With di-isopropyl azodicarboxylate; triphenylphosphine; In tetrahydrofuran; at 0 ℃; for 4h;
DOI:10.1016/S0968-0896(00)00047-X

Reference yield:

: 75-09-2
dichloromethane

: 2446-83-5
diisopropyl (E)-azodicarboxylate

: 163117-35-9
2-hydroxy-3'-carboethoxy-[1,1'-biphenyl]-6-carboxylic acid, ethyl ester

: 163117-49-5
3,4-didecyloxybenzyl alcohol

: 163117-60-0
2-[(3,4-bisdecyloxy)phenyl]methoxy-[1,1'-biphenyl]-6,3'-dicarboxylic acid, diethyl ester

Guidance literature:: With triphenylphosphine; In tetrahydrofuran; hexane;

Reference yield:

: 148-53-8
3-methoxy-2-hydroxybenzaldehyde

: 163117-60-0
2-[(3,4-bisdecyloxy)phenyl]methoxy-[1,1'-biphenyl]-6,3'-dicarboxylic acid, diethyl ester

Guidance literature:: Multi-step reaction with 6 steps

1: 74 percent / 4-dimethylaminopyridine / CH₂Cl₂ / 0.5 h / 0 °C

2: 94 percent / bis(triphenylphosphine)palladium dichloride; LiCl / dimethylformamide / 2.75 h / 150 °C

3: 100 percent / sulfamic acid; aq. sodium chlorite / tetrahydrofuran / 0.25 h / 0 °C

4: 0.432 g / conc. HCl / 24 h / Heating

5: 71 percent / dimethylboron bromide / 1,2-dichloro-ethane / 96 h / 20 °C

6: 44 percent / Ph₃P; diisopropylazodicarboxylate / tetrahydrofuran / 4 h / 0 °C

With hydrogenchloride; dmap; bis-triphenylphosphine-palladium(II) chloride; sodium chlorite; dimethylboron bromide; di-isopropyl azodicarboxylate; aminosulfonic acid; triphenylphosphine; lithium chloride; In tetrahydrofuran; dichloromethane; 1,2-dichloro-ethane; N,N-dimethyl-formamide; 1: trifluoromethylsulphonylation / 2: Condensation / 3: Oxidation / 4: Esterification / 5: demethylation / 6: Etherification;
DOI:10.1016/S0968-0896(00)00047-X