Z-1-Methoxy-3,3,3-trifluoropropene

Base Information

• Chemical Name: Z-1-Methoxy-3,3,3-trifluoropropene
• CAS No.: 26885-67-6
• Molecular Formula: C4H5 F3 O
• Molecular Weight: 126.078
• Hs Code.: 2909199090
• European Community (EC) Number: 802-111-7
• Mol file: 26885-67-6.mol

Synonyms:Z-1-Methoxy-3,3,3-trifluoropropene;26885-67-6;(z)-3,3,3-trifluoro-1-methoxyprop-1-ene;(Z)-1-Methoxy-3,3,3-trifluoropropene;SCHEMBL2483347;BGHDVJGMEWAMPO-IHWYPQMZSA-N;AKOS015850851;(Z)-3,3,3-Trifluoro-1-methoxy-propene;1-Propene,3,3,3-trifluoro-1-methoxy-,(1Z)-;A818652

Chemical Property of Z-1-Methoxy-3,3,3-trifluoropropene

Chemical Property:

• Vapor Pressure: 175.025mmHg at 25°C
• Boiling Point: 64.7°Cat760mmHg
• Flash Point: °C
• PSA: 9.23000
• Density: 1.136g/cm³
• LogP: 1.70880
• XLogP3: 1.6
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 1
• Exact Mass: 126.02924926
• Heavy Atom Count: 8
• Complexity: 83.8

Purity/Quality:

97% ^*data from raw suppliers

(Z)-1-Methoxy-3,3,3-trifluoropropene ^*data from reagent suppliers

Safty Information:

• Hazard Codes: F,Xi
• Statements: 10
• Safety Statements: 16

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: COC=CC(F)(F)F
• Isomeric SMILES: CO/C=C\C(F)(F)F

Technology Process of Z-1-Methoxy-3,3,3-trifluoropropene

There total 7 articles about Z-1-Methoxy-3,3,3-trifluoropropene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

methanol (67-56-1) + 2-bromo-3,3,3-trifluoropropene (1514-82-5) → (Z)-1-Methoxy-3,3,3-trifluoroprop-1-ene (26885-67-6)

Guidance literature:

With potassium hydroxide; for 1h;

DOI:10.1039/cc9960000057

Reference yield:

methanol (67-56-1) + (Z)-1-chloro-3,3,3-trifluoro-1-propene (99728-16-2) → E/Z-1-methoxy-3,3,3-trifluoropropene (26885-67-6,26885-71-2,406-89-3) + 3,3,3-trifluoroprop-1-yne (661-54-1)

Guidance literature:

With potassium hydroxide; at 38 ℃; for 5h; Autoclave;

Reference yield:

methanol (67-56-1) + 3,3,3-trifluoroprop-1-yne (661-54-1) → E/Z-1-methoxy-3,3,3-trifluoropropene (26885-67-6,26885-71-2,406-89-3)

Guidance literature:

With potassium hydroxide;

DOI:10.1016/j.jfluchem.2012.03.013

upstream raw materials:

methanol

3,3,3-trifluoroprop-1-yne

sodium methylate

(Z)-1-chloro-3,3,3-trifluoro-1-propene

Downstream raw materials:

3,3,3-trifluoropropanal

methane

1,1,1-trifluoro-3-methoxy-propane

3,3,3-trifluoropropanal dimethyl acetal