(S)-N-benzyl-1-((4S,5S)-5-((R)-3,3-diethyl-8,8,9,9-tetramethyl-4,7-dioxa-3,8-disiladecan-5-yl)-2,2-dimethyl-1,3-dioxolan-4-yl)but-3-en-1-amine

Base Information

Chemical Name:(S)-N-benzyl-1-((4S,5S)-5-((R)-3,3-diethyl-8,8,9,9-tetramethyl-4,7-dioxa-3,8-disiladecan-5-yl)-2,2-dimethyl-1,3-dioxolan-4-yl)but-3-en-1-amine
CAS No.:1233851-81-4
Molecular Formula:C₃₀H₅₅NO₄Si₂
Molecular Weight:549.942
Hs Code.:

Synonyms:(S)-N-benzyl-1-((4S,5S)-5-((R)-3,3-diethyl-8,8,9,9-tetramethyl-4,7-dioxa-3,8-disiladecan-5-yl)-2,2-dimethyl-1,3-dioxolan-4-yl)but-3-en-1-amine

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Chemical Property of (S)-N-benzyl-1-((4S,5S)-5-((R)-3,3-diethyl-8,8,9,9-tetramethyl-4,7-dioxa-3,8-disiladecan-5-yl)-2,2-dimethyl-1,3-dioxolan-4-yl)but-3-en-1-amine

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Technology Process of (S)-N-benzyl-1-((4S,5S)-5-((R)-3,3-diethyl-8,8,9,9-tetramethyl-4,7-dioxa-3,8-disiladecan-5-yl)-2,2-dimethyl-1,3-dioxolan-4-yl)but-3-en-1-amine

There total 4 articles about (S)-N-benzyl-1-((4S,5S)-5-((R)-3,3-diethyl-8,8,9,9-tetramethyl-4,7-dioxa-3,8-disiladecan-5-yl)-2,2-dimethyl-1,3-dioxolan-4-yl)but-3-en-1-amine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

: 994-30-9
triethylsilyl chloride

: 1233851-78-9
(R)-1-((4R,5S)-5-((S)-1-(benzylamino)-but-3-enyl)-2,2-dimethyl-1,3-dioxolan-4-yl)-2-(tert-butyl-dimethylsilyloxy)ethanol

: 1233851-81-4
(S)-N-benzyl-1-((4S,5S)-5-((R)-3,3-diethyl-8,8,9,9-tetramethyl-4,7-dioxa-3,8-disiladecan-5-yl)-2,2-dimethyl-1,3-dioxolan-4-yl)but-3-en-1-amine

Guidance literature:: With 1H-imidazole; In dichloromethane; at 0 ℃; for 0.166667h;
DOI:10.1016/j.tetlet.2010.04.011

Reference yield:

: 1233851-77-8
C₂₁H₃₅NO₄Si

: 1233851-81-4
(S)-N-benzyl-1-((4S,5S)-5-((R)-3,3-diethyl-8,8,9,9-tetramethyl-4,7-dioxa-3,8-disiladecan-5-yl)-2,2-dimethyl-1,3-dioxolan-4-yl)but-3-en-1-amine

Guidance literature:: Multi-step reaction with 2 steps

1: zinc / tetrahydrofuran / -15 - 20 °C

2: 1H-imidazole / dichloromethane / 0.17 h / 0 °C

With 1H-imidazole; zinc; In tetrahydrofuran; dichloromethane;
DOI:10.1016/j.tetasy.2011.07.009

Reference yield:

: 217309-46-1
5-(tert-butyldimethylsilyloxy)-2,3-isopropylidenedioxy-D-ribofuranose

: 1233851-81-4
(S)-N-benzyl-1-((4S,5S)-5-((R)-3,3-diethyl-8,8,9,9-tetramethyl-4,7-dioxa-3,8-disiladecan-5-yl)-2,2-dimethyl-1,3-dioxolan-4-yl)but-3-en-1-amine

Guidance literature:: Multi-step reaction with 3 steps

1: sodium sulfate / methanol / Reflux; Molecular sieve

2: zinc / tetrahydrofuran / -15 - 20 °C

3: 1H-imidazole / dichloromethane / 0.17 h / 0 °C

With 1H-imidazole; sodium sulfate; zinc; In tetrahydrofuran; methanol; dichloromethane;
DOI:10.1016/j.tetasy.2011.07.009