(Z)-[2-{(3R,4R,5R)-3,5-bis(tert-butyldimethylsilanyloxy)-2-methylene-4-(3-(tert-butyldiphenylsilanyloxy)propoxy)cyclohexylidene}ethyl]diphenylphosphine oxide

Base Information

Chemical Name:(Z)-[2-{(3R,4R,5R)-3,5-bis(tert-butyldimethylsilanyloxy)-2-methylene-4-(3-(tert-butyldiphenylsilanyloxy)propoxy)cyclohexylidene}ethyl]diphenylphosphine oxide
CAS No.:1254276-84-0
Molecular Formula:C₅₂H₇₅O₅PSi₃
Molecular Weight:895.395
Hs Code.:

(Z)-[2-{(3R,4R,5R)-3,5-bis(tert-butyldimethylsilanyloxy)-2-methylene-4-(3-(tert-butyldiphenylsilanyloxy)propoxy)cyclohexylidene}ethyl]diphenylphosphine oxide

Synonyms:(Z)-[2-{(3R,4R,5R)-3,5-bis(tert-butyldimethylsilanyloxy)-2-methylene-4-(3-(tert-butyldiphenylsilanyloxy)propoxy)cyclohexylidene}ethyl]diphenylphosphine oxide

Suppliers and Price of (Z)-[2-{(3R,4R,5R)-3,5-bis(tert-butyldimethylsilanyloxy)-2-methylene-4-(3-(tert-butyldiphenylsilanyloxy)propoxy)cyclohexylidene}ethyl]diphenylphosphine oxide

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (Z)-[2-{(3R,4R,5R)-3,5-bis(tert-butyldimethylsilanyloxy)-2-methylene-4-(3-(tert-butyldiphenylsilanyloxy)propoxy)cyclohexylidene}ethyl]diphenylphosphine oxide

Chemical Property:

Purity/Quality:: min 99%, ^*data from raw suppliers

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Technology Process of (Z)-[2-{(3R,4R,5R)-3,5-bis(tert-butyldimethylsilanyloxy)-2-methylene-4-(3-(tert-butyldiphenylsilanyloxy)propoxy)cyclohexylidene}ethyl]diphenylphosphine oxide

There total 22 articles about (Z)-[2-{(3R,4R,5R)-3,5-bis(tert-butyldimethylsilanyloxy)-2-methylene-4-(3-(tert-butyldiphenylsilanyloxy)propoxy)cyclohexylidene}ethyl]diphenylphosphine oxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

: ((1R,2R,3R,Z)-2-(3-(tert-butyldiphenylsilyloxy)propoxy)-5-(2-chloroethylidene)-4-methylenecyclohexane-1,3-diyl)bis(oxy)bis(tert-butyldimethylsilane)

: 829-85-6
diphenylphosphane

: 1254276-84-0
(Z)-[2-{(3R,4R,5R)-3,5-bis(tert-butyldimethylsilanyloxy)-2-methylene-4-(3-(tert-butyldiphenylsilanyloxy)propoxy)cyclohexylidene}ethyl]diphenylphosphine oxide

Guidance literature:: diphenylphosphane; With n-butyllithium; In tetrahydrofuran; at 0 ℃; for 0.5h;

((1R,2R,3R,Z)-2-(3-(tert-butyldiphenylsilyloxy)propoxy)-5-(2-chloroethylidene)-4-methylenecyclohexane-1,3-diyl)bis(oxy)bis(tert-butyldimethylsilane); In tetrahydrofuran; at -65 ℃; for 1h;

With dihydrogen peroxide; In chloroform; for 1h;

Reference yield: 80.0%

: ((1R,2R,3R,Z)-2-(3-(tert-butyldiphenylsilyloxy)propoxy)-5-(2-chloroethylidene)-4-methylenecyclohexane-1,3-diyl)bis(oxy)bis(tert-butyldimethylsilane)

: 65567-06-8,4541-02-0
lithium diphenylphosphide

: 1254276-84-0
(Z)-[2-{(3R,4R,5R)-3,5-bis(tert-butyldimethylsilanyloxy)-2-methylene-4-(3-(tert-butyldiphenylsilanyloxy)propoxy)cyclohexylidene}ethyl]diphenylphosphine oxide

Guidance literature:: ((1R,2R,3R,Z)-2-(3-(tert-butyldiphenylsilyloxy)propoxy)-5-(2-chloroethylidene)-4-methylenecyclohexane-1,3-diyl)bis(oxy)bis(tert-butyldimethylsilane); lithium diphenylphosphide; In tetrahydrofuran; hexane; at -60 ℃; for 1h; Inert atmosphere;

With dihydrogen peroxide; In chloroform; water; at 20 ℃; for 0.166667h; Inert atmosphere;
DOI:10.1021/acs.oprd.0c00436