(HO((CH₃)3C)2C₆H₂)2CHGeCl₃

Base Information

• Chemical Name: (HO((CH₃)3C)2C₆H₂)2CHGeCl₃
• CAS No.: 153789-55-0
• Molecular Formula: C₂₉H₄₃Cl₃GeO₂
• Molecular Weight: 602.608
• Mol file: 153789-55-0.mol

Synonyms:(HO((CH₃)3C)2C₆H₂)2CHGeCl₃

Chemical Property of (HO((CH₃)3C)2C₆H₂)2CHGeCl₃

Chemical Property:

Purity/Quality:

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Technology Process of (HO((CH₃)3C)2C₆H₂)2CHGeCl₃

There total 2 articles about (HO((CH₃)3C)2C₆H₂)2CHGeCl₃ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

Coppinger's Radikal (22719-43-3,2370-18-5) + germanium hydride trichloride (1184-65-2) → (HO((CH3)3C)2C6H2)2CHGeCl3 (153789-55-0) + 4,4'-Methylenebis(2,6-di-tert-butylphenol) (118-82-1) + 2,6-di-tert-butyl-4-(3,5-di-tert-butyl-4-hydroxy-benzylidene)-cyclohexa-2,5-dienone (4359-97-1)

Guidance literature:

With hydrogenchloride; In tetrahydrofuran; treatment od reaction mixt. in THF with HCl soln., stirring (15 min); org. phase sepn., drying over Na2SO4 (24 h), soln. concn.; identification of individual compds.;

Reference yield: 57.0%

Cl3Ge(1-)*(C2H5)3NH(1+)=Cl3Ge(C2H5)3NH (32073-52-2) + Coppinger's Radikal (22719-43-3,2370-18-5) → (HO((CH3)3C)2C6H2)2CHGeCl3 (153789-55-0) + 2,6-di-tert-butyl-4-(3,5-di-tert-butyl-4-hydroxy-benzylidene)-cyclohexa-2,5-dienone (4359-97-1)

Guidance literature:

In tetrahydrofuran; org. compd. soln. addn. to excess Ge-compd., mixt. refluxing for 2 h, stirring (2 h, room temp.), reaction mixt. filtration (celite); filtrate concn. (reduced pressure); identification of individual compds.;

Reference yield: 90.0%

(HO((CH3)3C)2C6H2)2CHGeCl3 (153789-55-0) + Coppinger's Radikal (22719-43-3,2370-18-5) + ethylmagnesium bromide (925-90-6) → (HO((CH3)3C)2C6H2)2CHGeH3 (153789-57-2) + hexaethyldigermane (993-62-4) + octaethyltrigermane (13937-05-8)

Guidance literature:

With lithium aluminium tetrahydride; water; In tetrahydrofuran; Ge-compd. soln. (THF) redn. with LiAlH4 soln. (ether) (0°C), hydrolyse; reaction soln. drying over Na2SO4, concn. (reduced pressure);

upstream raw materials:

Coppinger's Radikal

germanium hydride trichloride

Cl₃Ge^(1-)*(C₂H₅)3NH⁽¹⁺⁾=Cl₃Ge(C₂H₅)3NH

Downstream raw materials:

(HO((CH₃)3C)2C₆H₂)2CHGeH₃

hexaethyldigermane

octaethyltrigermane