Aminoferrocene

Base Information

• Chemical Name: Aminoferrocene
• CAS No.: 1273-82-1
• Molecular Formula: C10H11 Fe N
• Molecular Weight: 201.051
• Hs Code.: 29420000
• Mol file: 1273-82-1.mol

Synonyms:Ferrocenylamine(8CI); Iron, (aminocyclopentadienyl)cyclopentadienyl- (6CI,7CI);Aminoferrocene; Ferrocenamine

Chemical Property of Aminoferrocene

Chemical Property:

• Melting Point: 153-155 °C
• PSA: 26.02000
• LogP: 1.74080
• Storage Temp.: Refrigerator

Purity/Quality:

98%,99%, ^*data from raw suppliers

Aminoferrocene >96.0%(GC)(T) ^*data from reagent suppliers

Safty Information:

• Statements: -36/38
• Safety Statements: 26

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Aminoferrocene

There total 57 articles about Aminoferrocene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

azoferrocene → aminoferrocene (1273-82-1)

Guidance literature:

With hydrogenchloride; zinc; In ethanol; water; benzene;

Reference yield: 99.0%

N-ferrocenyl phthalimide (1294-21-9) → aminoferrocene (1273-82-1)

Guidance literature:

With hydrazine hydrate; In ethanol; for 2h; Reflux; Inert atmosphere; Schlenk technique; Glovebox;

DOI:10.1039/c9dt03808f

Reference yield: 99.0%

N-ferrocenyl phthalimide (1294-21-9) + hydrazine hydrate (7803-57-8,79785-97-0) → aminoferrocene (1273-82-1)

Guidance literature:

In ethanol; Ar, hydrazine added to a soln. of Fe compd., refluxed for 2 h; cooled to ambient temp., water added, extd. (diethyl ether), extract dried (Na2SO4), evapd. (vac.) to dryness; elem. anal.;

DOI:10.1002/ejic.200300897

upstream raw materials:

lithium aluminium tetrahydride

O-Methylhydroxylamin

lithiumferrocene

N-benzyloxyamine

Downstream raw materials:

ferrocene

iron(II) oxalate

N-ferrocenyl-3-(ethylcarboxylate)benzene-1-carboxamide

C₂₀H₁₉FeNO₄

Refernces

• 1、 Manibalan, Kesavan,Mani, Veerappan,Huang, Sheng-Tung. "A switchable electrochemical redox ratiometric substrate based on ferrocene for highly selective and sensitive fluoride detection". . p. 71727 - 71732. Retrieved 2016.
• 2、 Okamura, Taka-Aki,Sakauye, Keiko,Doi, Mototsugu,Yamamoto, Hitoshi,Ueyama, Norikazu,Nakamura, Akira. "Observation of a large current on the cyclic voltammetry of acylaminoferrocenes in the solid state: An efficient electron-transfer pathway through continuous NH...O=C hydrogen-bond chains and π-conjugation". . p. 1270 - 1278. Retrieved 2005.
• 3、 Chang, Yu-Wei,Huang, Min-Jie,Lai, Cheng-Chang,Chang, Ching-Chih,Huang, Man-Ping,Liao, Chuang-Yi,Cheng, Chien-Hong. "A versatile ferrocene-containing material as a p-type charge generation layer for high-performance full color tandem OLEDs". . p. 14294 - 14297. Retrieved 2016.
• 4、 Lacina, Karel,Konhefr, Martin,Novotny, Jan,Potě?il, David,Zdráhal, Zbyněk,Skládal, Petr. "Combining ferrocene, thiophene and a boronic acid: A hybrid ligand for reagentless electrochemical sensing of cis-diols". . p. 3235 - 3238. Retrieved 2014.
• 5、 Rios Yepes, Yersica,Martínez, Javier,Rangel Sánchez, Hiram,Quintero, Celso,Ortega-Alfaro, M. Carmen,López-Cortés, José G.,Daniliuc, Constantin G.,Anti?olo, Antonio,Ramos, Alberto,Rojas, René S.. "Aluminum complexes with new non-symmetric ferrocenyl amidine ligands and their application in CO2 transformation into cyclic carbonates". . p. 1124 - 1134. Retrieved 2020.
• 6、 Lim, Young-Kwan,Wallace, Scott,Bollinger, John C.,Chen, Xufang,Lee, Dongwhan. "Triferrocenes built on a C3-symmetric ligand platform: Entry to redox-active pseudo-triphenylenes via chelation-driven stereoselection of triple Schiff bases". . p. 1694 - 1703. Retrieved 2007.
• 7、 Hartley, A. M.,Visco, R. E.. "". . p. 1871 - 1874. Retrieved 1963.
• 8、 Grubert, H.,Rinehart, K. L.. "". . . Retrieved 1959.
• 9、 ?utalo, Petar,Kodrin, Ivan,Nuskol, Marko,Semen?i?, Mojca ?aki?. "Sensing of the Induced Helical Chirality by the Chiroptical Response of the Ferrocene Chromophore". . . Retrieved 2021/12/27.
• 10、 Carter, Cole,Kratish, Yosi,Jurca, Titel,Gao, Yanshan,Marks, Tobin J.. "Bis-ferrocenyl-pyridinediimine trinuclear mixed-valent complexes with metal-binding dependent electronic coupling: Synthesis, structures, and redox-spectroscopic characterization". . p. 18715 - 18729. Retrieved 2020/11/17.