diethyl (3-methoxyphenyl)methylpropanedioate

Base Information

Chemical Name:diethyl (3-methoxyphenyl)methylpropanedioate
CAS No.:83026-48-6
Molecular Formula:C₁₅H₂₀O₅
Molecular Weight:280.321
Hs Code.:

Synonyms:diethyl (3-methoxyphenyl)methylpropanedioate

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of diethyl (3-methoxyphenyl)methylpropanedioate

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Technology Process of diethyl (3-methoxyphenyl)methylpropanedioate

There total 6 articles about diethyl (3-methoxyphenyl)methylpropanedioate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 50874-07-2
2-(3-methoxyphenyl)malonic acid diethyl ester

: 74-88-4
methyl iodide

: 83026-48-6
diethyl (3-methoxyphenyl)methylpropanedioate

Guidance literature:: With sodium hydride; In 1,2-dimethoxyethane; paraffin; for 18h; Ambient temperature; 1.) room temp., 40 min;
DOI:10.3987/COM-96-7421

Reference yield: 57.0%

: 79421-99-1
tris(3-methoxyphenyl)-1,3,5,2,4,6-trioxatriborinane

: 609-08-5
Diethyl methylmalonate

: 83026-48-6
diethyl (3-methoxyphenyl)methylpropanedioate

Guidance literature:: With cesium acetate; copper(II) bis(trifluoromethanesulfonate); triethylamine; In 1,2-dichloro-ethane; at 20 ℃; for 72h; Glovebox; Inert atmosphere;
DOI:10.1002/anie.201510558

Reference yield:

: 2398-37-0
3-methoxyphenyl bromide

: 83026-48-6
diethyl (3-methoxyphenyl)methylpropanedioate

Guidance literature:: Multi-step reaction with 3 steps

1: 1.) Mg / 1.) THF, 2a.) ether, -78 deg C, 2b.) 20 deg C, 1.5 h

2: 86 percent / Et₃N, 4-(dimethylamino)pyridine / CH₂Cl₂ / 48 h / 20 °C

3: 1.) sodium α-(dimethylamino)naphthalenide / 1.) benzene, HMPA, 30 s, 2.) 30 min

With dmap; sodium α-(dimethylamino)naphthalenide; magnesium; triethylamine; In dichloromethane;
DOI:10.1021/jo00145a017