Thiophosphorochloridic acid O-(4-bromo-2,5-dichloro-phenyl) ester O'-ethyl ester

Base Information

• Chemical Name: Thiophosphorochloridic acid O-(4-bromo-2,5-dichloro-phenyl) ester O'-ethyl ester
• CAS No.: 55999-27-4
• Molecular Formula: C₈H₇BrCl₃O₂PS
• Molecular Weight: 384.445
• Mol file: 55999-27-4.mol

Synonyms:Thiophosphorochloridic acid O-(4-bromo-2,5-dichloro-phenyl) ester O'-ethyl ester

Chemical Property of Thiophosphorochloridic acid O-(4-bromo-2,5-dichloro-phenyl) ester O'-ethyl ester

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Thiophosphorochloridic acid O-(4-bromo-2,5-dichloro-phenyl) ester O'-ethyl ester

There total 1 articles about Thiophosphorochloridic acid O-(4-bromo-2,5-dichloro-phenyl) ester O'-ethyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 44.0%

O-ethyl dichlorothiophosphate (1498-64-2) + 4-bromo-2,5-dichlorophenol (1940-42-7,79151-08-9) → Thiophosphorochloridic acid O-(4-bromo-2,5-dichloro-phenyl) ester O'-ethyl ester (55999-27-4)

Guidance literature:

With potassium carbonate; In acetonitrile; at 20 ℃; for 1h;

DOI:10.1021/jf025703+

Reference yield: 69.0%

4-(methylamino)butyric acid (1119-48-8) + Thiophosphorochloridic acid O-(4-bromo-2,5-dichloro-phenyl) ester O'-ethyl ester (55999-27-4) → 4-{[(4-bromo-2,5-dichloro-phenoxy)-ethoxy-thiophosphoryl]-methyl-amino}-butyric acid (475476-68-7)

Guidance literature:

With potassium hydroxide; In methanol; for 0.0833333h;

DOI:10.1021/jf025703+

Reference yield: 40.0%

Thiophosphorochloridic acid O-(4-bromo-2,5-dichloro-phenyl) ester O'-ethyl ester (55999-27-4) + 5-aminopentanoic acid (660-88-8) → 5-[(4-bromo-2,5-dichloro-phenoxy)-ethoxy-thiophosphorylamino]-pentanoic acid (475476-66-5)

Guidance literature:

With potassium hydroxide; In methanol; for 0.0833333h;

DOI:10.1021/jf025703+

upstream raw materials:

O-ethyl dichlorothiophosphate

4-bromo-2,5-dichlorophenol

Downstream raw materials:

phosphorothioic acid, O-(4-bromo-2,5-dichlorophenyl)-O-ethyl S-propylester

4-{[(4-bromo-2,5-dichloro-phenoxy)-ethoxy-thiophosphoryl]-methyl-amino}-butyric acid

4-[(4-bromo-2,5-dichloro-phenoxy)-ethoxy-thiophosphorylamino]-butyric acid

5-[(4-bromo-2,5-dichloro-phenoxy)-ethoxy-thiophosphorylamino]-pentanoic acid