benzyl 6-methylhept-5-enoate

Base Information

• Chemical Name: benzyl 6-methylhept-5-enoate
• CAS No.: 108957-11-5
• Molecular Formula: C₁₅H₂₀O₂
• Molecular Weight: 232.323
• Mol file: 108957-11-5.mol

Synonyms:benzyl 6-methylhept-5-enoate

Chemical Property of benzyl 6-methylhept-5-enoate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of benzyl 6-methylhept-5-enoate

There total 3 articles about benzyl 6-methylhept-5-enoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 55.0%

2-bromoprop-1-ene (557-93-7) + benzyl 4-bromobutanoate (126430-46-4) → propene (187737-37-7,13987-01-4,15220-87-8,9003-07-0,676-63-1,25085-53-4) + octanedioic acid dibenzyl ester (42413-23-0) + benzyl butanoate (103-37-7) + 2,3-dimethyl-buta-1,3-diene (513-81-5) + benzyl 6-methylhept-5-enoate (108957-11-5)

Guidance literature:

With pyridine; 1,3-dimethyl-3,4,5,6-tetrahydro-2(1H)-pyrimidinone; 4,4'-Dimethoxy-2,2'-bipyridin; NiI₂*3.5H₂O; sodium iodide; zinc; at 20 - 60 ℃; for 25h; chemoselective reaction;

DOI:10.1021/ja301769r

Reference yield: 48.0%

2-methylbut-3-en-2-yl(tributyl)stannane (53911-92-5,104108-29-4) + Benzyl 3-iodopropanoate (93415-08-8) → prenyl tributylstannane (104108-29-4) + benzyl 6-methylhept-5-enoate (108957-11-5)

Guidance literature:

With catalyst: azobisisobutyronitrile; In toluene; refluxed for 48 h;

DOI:10.1039/c39860001339

Reference yield:

2-methylbut-3-en-2-yl(tributyl)stannane (53911-92-5,104108-29-4) + Benzyl 3-iodopropanoate (93415-08-8) → benzyl 6-methylhept-5-enoate (108957-11-5)

Guidance literature:

2,2'-azobis(isobutyronitrile); In toluene; for 48h; Yield given; Heating;

DOI:10.1039/c39860001339

upstream raw materials:

2-methylbut-3-en-2-yl(tributyl)stannane

Benzyl 3-iodopropanoate

2-bromoprop-1-ene

benzyl 4-bromobutanoate

Refernces

• 1、 Baldwin, Jack E.,Adlington, Robert M.,Birch, David J.,Crawford, James A.,Sweeney, Joseph B.. "Radical Reactions in Synthesis: Carbon-Carbon Bond Formation from 2-Substituted Allyl Trialkyl Stannanes". . p. 1339 - 1340. Retrieved 2007/10/02.