Tributyl(3-methyl-2-butenyl)tin

Base Information Edit

Chemical Name:Tributyl(3-methyl-2-butenyl)tin
CAS No.:53911-92-5
Molecular Formula:C₁₇H₃₆Sn
Molecular Weight:359.183
Hs Code.:29312000
European Community (EC) Number:624-983-6
DSSTox Substance ID:DTXSID30370465
Mol file:53911-92-5.mol

Synonyms:53911-92-5;Tributyl(3-methyl-2-butenyl)tin;tributyl(3-methylbut-2-en-1-yl)stannane;tributyl(3-methylbut-2-enyl)stannane;tributylprenylstannane;Stannane, tributyl(3-methyl-2-butenyl)-;DTXSID30370465;3-Methyl-2-butenyltributylstannane;MFCD01863649;Tri-n-butyl(3-methyl-2-butenyl)tin;AKOS024462382;Tributyl(3-methyl-2-butenyl)tin, 90%;AS-64352

Suppliers and Price of Tributyl(3-methyl-2-butenyl)tin

Supply Marketing:Edit

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Sigma-Aldrich
Tributyl(3-methyl-2-butenyl)tin 90%
1g
$ 72.80

American Custom Chemicals Corporation
TRIBUTYL(3-METHYL-2-BUTENYL)TIN 95.00%
1G
$ 678.66

Alfa Aesar
Tri-n-butyl(3-methyl-2-butenyl)tin, 95%
5g
$ 229.00

Alfa Aesar
Tri-n-butyl(3-methyl-2-butenyl)tin, 95%
1g
$ 63.80

Total 17 raw suppliers

Chemical Property of Tributyl(3-methyl-2-butenyl)tin Edit

Chemical Property:

Vapor Pressure:0.000117mmHg at 25°C
Refractive Index: ">
Boiling Point:346.3°Cat760mmHg
Flash Point:167.5°C
PSA：0.00000
Density:g/cm³
LogP:6.80170
Storage Temp.:Refrigerator (+4°C)
Water Solubility.:Immiscible with water.
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:0
Rotatable Bond Count:11
Exact Mass:360.183904
Heavy Atom Count:18
Complexity:192

Purity/Quality:

98%,99%, ^*data from raw suppliers

Tributyl(3-methyl-2-butenyl)tin 90% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:T,N
Statements: 21-25-36/38-48/23/25-50/53
Safety Statements: 35-36/37/39-45-60-61

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

Canonical SMILES:CCCC[Sn](CCCC)(CCCC)CC=C(C)C
Uses Tri-n-butyl(3-methyl-2-butenyl)tin is used in prenylation of ethyl propiolate. It is also involved in chemical research.

Technology Process of Tributyl(3-methyl-2-butenyl)tin

There total 2 articles about Tributyl(3-methyl-2-butenyl)tin which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 1461-22-9
tributyltin chloride

: 870-63-3
prenyl bromide

: 53911-92-5,104108-29-4
2-methylbut-3-en-2-yl(tributyl)stannane

: 115991-75-8
2-methyl-2-butenyltributyltin

Guidance literature:: With ammonium chloride; zinc; In tetrahydrofuran; water; appropriate alkyltin chloride is added to THF/H2O mixt. with excess of zinc powder, appropriate allyl bromide is added dropwise under stirring within 5 min, mixt. is stirred for 30 min; extn. (petroleum ether), separated org. layer is washed (aq. NaCl), drying (MgSO4), solvent is removed, distn., mixt. of isomers 3-methyl-1-buten-3-yltributyltin and 2-methyl-2-butenyltributyltin ratio 40:60; total yield 62%;
DOI:10.1021/om00015a025

Reference yield:

: 104108-29-4
prenyl tributylstannane

: 53911-92-5,104108-29-4
2-methylbut-3-en-2-yl(tributyl)stannane

Guidance literature:: With 2,2,6,6-tetramethyl-piperidine-N-oxyl; In benzene; Irradiation (UV/VIS); N2; Sn-compd. soln. irradiation with 300 W high-pressure Hg lamp throughsatd. aq. CuSO4 soln. (280 nm) for 3 h, solvent evapn. (reduced pressur e);
DOI:10.1039/a707609f