dichlorotris(triphenylstibine)ruthenium(II)

Base Information

Chemical Name:dichlorotris(triphenylstibine)ruthenium(II)
CAS No.:15709-80-5
Molecular Formula:C₅₄H₄₅Cl₂RuSb₃
Molecular Weight:1231.18
Hs Code.:

Synonyms:dichlorotris(triphenylstibine)ruthenium(II)

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Chemical Property of dichlorotris(triphenylstibine)ruthenium(II)

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Technology Process of dichlorotris(triphenylstibine)ruthenium(II)

There total 2 articles about dichlorotris(triphenylstibine)ruthenium(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 14898-67-0
ruthenium(III) chloride trihydrate

: 603-36-1
triphenylantimony

: 15709-80-5
{RuCl₂(C₁₈H₁₅Sb)3}

Guidance literature:: With zinc amalgame; In not given; alcoholic soln. of RuCl3 was refluxed under N2 with zinc amalgame for 30 min; zinc was removed from soln., soln. of ligand was added, prepd. mixture was refluxed for 2.5 h; filtration, washing with MeOH, recrystn. from alcohol; elem. anal.;
DOI:10.1016/S0277-5387(00)84383-1

Reference yield:

: 20759-14-2,14898-67-0
ruthenium(III) chloride hydrate

: 603-36-1
triphenylantimony

: 15709-80-5
{RuCl₂(C₁₈H₁₅Sb)3}

Guidance literature:: In methanol; from a soln. of 0.2 g RuCl3*3H2O in 50 ml methanol or 2-methoxy-ethanol by addition of 1.7 g stibine; the filtrate is shaken for 10 min;; washing with methanol and ether; drying in vacuum at 60°C;;
DOI:10.1016/0022-1902(66)80191-4

Reference yield: 75.0%

: 243643-58-5
mer-[(1,4-bis(diphenylphosphino)butane)aquatrichlororuthenium(III)]

: 15709-80-5
{RuCl₂(C₁₈H₁₅Sb)3}

: [(triphenylstibine)ClRu-(μ-Cl)3-RuCl(1,4-bis(diphenylphosphino)butane)]

Guidance literature:: In dichloromethane; byproducts: triphenylstibane, H2O; all manipulations under purified Ar atm.; suspn. of Ru compds. in CH2Cl2stirred at room temp. for 3 h; concd., pptd. with n-hexane, collected, washed well with MeOH and n-hexane, dried in vac.; elem. anal.;
DOI:10.1016/j.poly.2004.09.028