DIMETHYL IODOTEREPHTHALATE

Base Information

• Chemical Name: DIMETHYL IODOTEREPHTHALATE
• CAS No.: 165534-79-2
• Molecular Formula: C10H9IO4
• Molecular Weight: 320.084
• Hs Code.: 2917399090
• Mol file: 165534-79-2.mol

Synonyms:Dimethyl iodoterephthalate;Dimethyl 2-iodoterephthalate;1,4-Benzenedicarboxylicacid, 2-iodo-, dimethyl ester (9CI);

Chemical Property of DIMETHYL IODOTEREPHTHALATE

Chemical Property:

• Vapor Pressure: 3.97E-05mmHg at 25°C
• Melting Point: 81 °C
• Refractive Index: 1.584
• Boiling Point: 352 °C at 760 mmHg
• Flash Point: 166.7 °C
• PSA: 52.60000
• Density: 1.708g/cm³
• LogP: 1.86440
• Storage Temp.: 2-8°C(protect from light)

Purity/Quality:

97% ^*data from raw suppliers

Dimethyl2-Iodoterephthalate ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36/37/39

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of DIMETHYL IODOTEREPHTHALATE

There total 9 articles about DIMETHYL IODOTEREPHTHALATE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

2-iodo-1,4-benzenedicarboxylic acid (1829-22-7) + methyl iodide (74-88-4) → dimethyl 2-iodoterephthalate (165534-79-2)

Guidance literature:

2-iodo-1,4-benzenedicarboxylic acid; With potassium carbonate; In N,N-dimethyl-formamide; at 20 ℃; for 0.5h;

methyl iodide; In N,N-dimethyl-formamide; at 20 ℃; for 1h;

DOI:10.1016/j.bmcl.2014.05.037

Reference yield: 68.0%

methanol (67-56-1) + C8H3Cl2IO2 → dimethyl 2-iodoterephthalate (165534-79-2)

Guidance literature:

With triethylamine; at 0 - 20 ℃;

DOI:10.1002/anie.201509702

Reference yield: 64.0%

dimethyl aminoterephthalate (5372-81-6) → dimethyl 2-iodoterephthalate (165534-79-2)

Guidance literature:

dimethyl aminoterephthalate; With sulfuric acid; sodium nitrite; In water; at 0 - 5 ℃; for 1h;

With potassium iodide; In water; at 60 ℃; for 0.333333h;

DOI:10.1039/c1jm14682c

upstream raw materials:

methanol

2-iodo-1,4-benzenedicarboxylic acid

hydrogenchloride

3-iodo-4-toluic acid

Downstream raw materials:

C₅₆H₅₇B₂N₃O₄S

C₅₆H₅₇B₂N₃O₄S

C₂₆H₂₁NO₂S

C₄₂H₄₃N₃S