[N-[1,1-dimethyl-2-(ethylimino-κN)propyl]-2,6-bis(1-methylethyl)benzenaminato-κN]triiodohafnium

Base Information

Chemical Name:[N-[1,1-dimethyl-2-(ethylimino-κN)propyl]-2,6-bis(1-methylethyl)benzenaminato-κN]triiodohafnium
CAS No.:1262405-08-2
Molecular Formula:C₁₉H₃₁HfI₃N₂
Molecular Weight:846.672
Hs Code.:

Synonyms:[N-[1,1-dimethyl-2-(ethylimino-κN)propyl]-2,6-bis(1-methylethyl)benzenaminato-κN]triiodohafnium

Suppliers and Price of [N-[1,1-dimethyl-2-(ethylimino-κN)propyl]-2,6-bis(1-methylethyl)benzenaminato-κN]triiodohafnium

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of [N-[1,1-dimethyl-2-(ethylimino-κN)propyl]-2,6-bis(1-methylethyl)benzenaminato-κN]triiodohafnium

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of [N-[1,1-dimethyl-2-(ethylimino-κN)propyl]-2,6-bis(1-methylethyl)benzenaminato-κN]triiodohafnium

There total 2 articles about [N-[1,1-dimethyl-2-(ethylimino-κN)propyl]-2,6-bis(1-methylethyl)benzenaminato-κN]triiodohafnium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.3%

: 1262405-05-9
[N-[1,1-dimethyl-2-(ethylimino-κN)propyl]-2,6-bis(1-methylethyl)benzenaminato-κN]tris(phenylmethyl)hafnium

: 7553-56-2,12190-71-5,8031-47-8
iodine

: 1262405-08-2
[N-[1,1-dimethyl-2-(ethylimino-κN)propyl]-2,6-bis(1-methylethyl)benzenaminato-κN]triiodohafnium

Guidance literature:: In dichloromethane; (N2); std. Schlenk technique; soln. of I2 (3 equiv.) in CH2Cl2 was addedto soln. of Hf complex in CH2Cl2 within 10 min; stirred for 2 h; evapd. (vac.); crystd. (CH2Cl2/hexane, -40°C); elem. anal.;
DOI:10.1021/om1008742

Reference yield:

: N-[1,1-dimethyl-2-(ethylimino)propyl]-2,6-bis-(1-methylethyl)benzenamine

: 1262405-08-2
[N-[1,1-dimethyl-2-(ethylimino-κN)propyl]-2,6-bis(1-methylethyl)benzenaminato-κN]triiodohafnium

Guidance literature:: Multi-step reaction with 2 steps

1: toluene

2: dichloromethane

In dichloromethane; toluene;
DOI:10.1021/om1008742

Reference yield: 44.4%

: 1262405-08-2
[N-[1,1-dimethyl-2-(ethylimino-κN)propyl]-2,6-bis(1-methylethyl)benzenaminato-κN]triiodohafnium

: 41251-37-0
methyl-d3-magnesium iodide

: 1262405-07-1
[N-[1,1-dimethyl-2-(ethylimino-κN)propyl]-2,6-bis(1-methylethyl)benzenaminato-κN]tri(methyl-d3)hafnium

Guidance literature:: In tetrahydrofuran; diethyl ether; (N2); std. Schlenk technique; soln. of CD3MgI (3 equiv.) in ether was added to soln. of hf complex in THF; stirred for 2 h; filtered; evapd. (vac.); dissolved in hexane; filtered; decanted; washed(cold hexane); dried (vac.); elem. anal.;
DOI:10.1021/om1008742