[PtMe(N,N'-bis(2,6-diisopropylphenyl)butane-2,3-diimine)(ethylene)]BF₄

Base Information

• Chemical Name: [PtMe(N,N'-bis(2,6-diisopropylphenyl)butane-2,3-diimine)(ethylene)]BF₄
• CAS No.: 199284-74-7
• Molecular Formula: BF₄*C₃₁H₄₇N₂Pt
• Molecular Weight: 729.612
• Mol file: 199284-74-7.mol

Synonyms:[PtMe(N,N'-bis(2,6-diisopropylphenyl)butane-2,3-diimine)(ethylene)]BF₄

Chemical Property of [PtMe(N,N'-bis(2,6-diisopropylphenyl)butane-2,3-diimine)(ethylene)]BF₄

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [PtMe(N,N'-bis(2,6-diisopropylphenyl)butane-2,3-diimine)(ethylene)]BF₄

There total 3 articles about [PtMe(N,N'-bis(2,6-diisopropylphenyl)butane-2,3-diimine)(ethylene)]BF₄ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

silver tetrafluoroborate (14104-20-2) + ethene (74-85-1) + [PtCl(Me)(diacetyl bis(2,6-diisopropylphenylimine))] (199284-91-8) → [Pt(Me)(diacetyl bis(2,6-diisopropylphenylimine))(ethylene)](BF4) (199284-74-7)

Guidance literature:

In dichloromethane; byproducts: AgCl; mixing AgBF4 and excess of ethylene, addn. of Pt-complex at 273 K, stirring for 48 h at room temp.; filtration off of AgCl (Celite), concn., crystn. on addn. of MePh and standing at 277 K, washing (MePh, pentane), drying (vac.); NMR spectroscopy;

DOI:10.1021/om970428f

Reference yield:

1,4-di(2,6-diisopropylphenyl)-2,3-dimethyl-1,4-diazabutadiene → [Pt(Me)(diacetyl bis(2,6-diisopropylphenylimine))(ethylene)](BF4) (199284-74-7)

Guidance literature:

Multi-step reaction with 2 steps

1: diethyl ether

2: dichloromethane

In diethyl ether; dichloromethane;

DOI:10.1021/om970428f

Reference yield:

tetrafluoroboric acid + [PtMe(N,N'-(1,2-dimethyl-1,2-ethanediylidene)bis(2,6-diisopropylaniline)))(ethylene)] (691894-16-3) → [PtMe(N,N'-bis(2,6-diisopropylphenyl)butane-2,3-diimine)(ethylene)]BF4 (199284-74-7)

Guidance literature:

In diethyl ether; chloroform; ethereal HBF4 was added to soln. of Pt complex in CHCl3;

DOI:10.1021/om049968k

upstream raw materials:

silver tetrafluoroborate

ethene

[PtCl(Me)(diacetyl bis(2,6-diisopropylphenylimine))]

[PtMe(N,N'-(1,2-dimethyl-1,2-ethanediylidene)bis(2,6-diisopropylaniline)))(ethylene)]

Downstream raw materials:

[PtMe(N,N'-(1,2-dimethyl-1,2-ethanediylidene)bis(2,6-diisopropylaniline)))(ethylene)]