(S,S,S)-[(S)-10-TMS-9-borabicylo[3.3.2]decane-9-yl)OCH(C₆H₄OMe-p)CH(CHCH₂)C(Ph)(Me)O[(S)-10-Ph-9-borabicyclo[3.3.2]decane-9-yl]

Base Information

• Chemical Name: (S,S,S)-[(S)-10-TMS-9-borabicylo[3.3.2]decane-9-yl)OCH(C₆H₄OMe-p)CH(CHCH₂)C(Ph)(Me)O[(S)-10-Ph-9-borabicyclo[3.3.2]decane-9-yl]
• CAS No.: 1105697-28-6
• Molecular Formula: C₄₆H₆₄B₂O₃Si
• Molecular Weight: 714.72

Synonyms:(S,S,S)-[(S)-10-TMS-9-borabicylo[3.3.2]decane-9-yl)OCH(C₆H₄OMe-p)CH(CHCH₂)C(Ph)(Me)O[(S)-10-Ph-9-borabicyclo[3.3.2]decane-9-yl]

Chemical Property of (S,S,S)-[(S)-10-TMS-9-borabicylo[3.3.2]decane-9-yl)OCH(C₆H₄OMe-p)CH(CHCH₂)C(Ph)(Me)O[(S)-10-Ph-9-borabicyclo[3.3.2]decane-9-yl]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (S,S,S)-[(S)-10-TMS-9-borabicylo[3.3.2]decane-9-yl)OCH(C₆H₄OMe-p)CH(CHCH₂)C(Ph)(Me)O[(S)-10-Ph-9-borabicyclo[3.3.2]decane-9-yl]

There total 3 articles about (S,S,S)-[(S)-10-TMS-9-borabicylo[3.3.2]decane-9-yl)OCH(C₆H₄OMe-p)CH(CHCH₂)C(Ph)(Me)O[(S)-10-Ph-9-borabicyclo[3.3.2]decane-9-yl] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

trans-(S)-[(S)-10-TMS-9-borabicyclo[3.3.2]decane-9-yl]CH2CHCHC(Ph)(Me)O[(S)-10-Ph-9-borabicyclo[3.3.2]decane-9-yl] + 4-methoxy-benzaldehyde (123-11-5) → (S,S,S)-[(S)-10-TMS-9-borabicylo[3.3.2]decane-9-yl)OCH(C6H4OMe-p)CH(CHCH2)C(Ph)(Me)O[(S)-10-Ph-9-borabicyclo[3.3.2]decane-9-yl] (1105697-28-6)

Guidance literature:

In tetrahydrofuran; at -78 ℃; for 12h; stereoselective reaction; Inert atmosphere;

Reference yield:

trans-((R)-10-Ph-9-borabicyclo[3.3.2]decane-9-yl)CH2CHCH((R)-10-TMS-9-borabicyclo[3.3.2]decane-9-yl) (1105697-26-4) + trans-((R)-10-Ph-9-borabicyclo[3.3.2]decane-9-yl)CHCHCH2((R)-10-TMS-9-borabicyclo[3.3.2]decane-9-yl) (1105697-27-5) + 4-methoxy-benzaldehyde (123-11-5) + acetophenone (98-86-2) → (R,R,R)-[(R)-10-TMS-9-borabicylo[3.3.2]decane-9-yl)OCH(C6H4OMe-p)CH(CHCH2)C(Ph)(Me)O[(R)-10-Ph-9-borabicyclo[3.3.2]decane-9-yl] (1105697-28-6)

Guidance literature:

In tetrahydrofuran; treatment of boron compd. with ketone deriv. in THF at 25°C for 3.5 h, treatment with aldehyde deriv. in THF at -78°C for 12 h; not isolated;

Reference yield:

B-[(E)-γ-(10S)-trimethylsilyl-9-borabicyclo[3.3.2]decane]allyl-(10S)-phenyl-9-borabicyclo[3.3.2]decane (1105697-26-4) + B-[(E)-γ-(10S)-phenyl-9-borabicyclo[3.3.2]decane]allyl-(10S)-trimethylsilyl-9-borabicyclo[3.3.2]decane (1105697-27-5) + 4-methoxy-benzaldehyde (123-11-5) + acetophenone (98-86-2) → (S,S,S)-[(S)-10-TMS-9-borabicylo[3.3.2]decane-9-yl)OCH(C6H4OMe-p)CH(CHCH2)C(Ph)(Me)O[(S)-10-Ph-9-borabicyclo[3.3.2]decane-9-yl] (1105697-28-6)

Guidance literature:

In tetrahydrofuran; treatment of mixt. of borane compds. with acetophenone in THF at -78°C for 12 h, treatment with aldehyde deriv. at -78°C for 12 h; NMR;

upstream raw materials:

trans-((R)-10-Ph-9-borabicyclo[3.3.2]decane-9-yl)CH₂CHCH((R)-10-TMS-9-borabicyclo[3.3.2]decane-9-yl)

trans-((R)-10-Ph-9-borabicyclo[3.3.2]decane-9-yl)CHCHCH₂((R)-10-TMS-9-borabicyclo[3.3.2]decane-9-yl)

4-methoxy-benzaldehyde

acetophenone

Downstream raw materials:

(1R,2R,3R)-1-(4-methoxyphenyl)-3-phenyl-2-vinylbutane-1,3-diol

(1S,2S,3S)-1-(4-methoxyphenyl)-3-phenyl-2-vinylbutane-1,3-diol

Post a RFQ

Cas No.:

Product Name:

Quantity:

Please select Metric Ton KG G Pound L ML

Email:

Company name:

Valid Period:

Detailed Requirements:

• Sample
• MOQ
• GMP
• FDA
• Price
  FOB CIF CFR EXW
• Urgent purchase

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

Remove

Submit

1

What can I do for you?
Get Best Price

Get Best Price for 1105697-28-6 (S,S,S)-[(S)-10-TMS-9-borabicylo[3.3.2]decane-9-yl)OCH(C₆H₄OMe-p)CH(CHCH₂)C(Ph)(Me)O[(S)-10-Ph-9-borabicyclo[3.3.2]decane-9-yl]

Send

Send

Metric Ton KG G Pound L ML

Send

Send