p-methoxyphenyl 2,3-anhydro-6-O-(tert-butyldimethylsilyl)-4-O-methyl-α-D-allopyranoside

Base Information

Chemical Name:p-methoxyphenyl 2,3-anhydro-6-O-(tert-butyldimethylsilyl)-4-O-methyl-α-D-allopyranoside
CAS No.:1449491-90-0
Molecular Formula:C₂₀H₃₂O₆Si
Molecular Weight:396.556
Hs Code.:

Synonyms:p-methoxyphenyl 2,3-anhydro-6-O-(tert-butyldimethylsilyl)-4-O-methyl-α-D-allopyranoside

Suppliers and Price of p-methoxyphenyl 2,3-anhydro-6-O-(tert-butyldimethylsilyl)-4-O-methyl-α-D-allopyranoside

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Total 1 raw suppliers

Chemical Property of p-methoxyphenyl 2,3-anhydro-6-O-(tert-butyldimethylsilyl)-4-O-methyl-α-D-allopyranoside

Chemical Property:

Purity/Quality:: 95%-98% ^*data from raw suppliers

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Technology Process of p-methoxyphenyl 2,3-anhydro-6-O-(tert-butyldimethylsilyl)-4-O-methyl-α-D-allopyranoside

There total 3 articles about p-methoxyphenyl 2,3-anhydro-6-O-(tert-butyldimethylsilyl)-4-O-methyl-α-D-allopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

: 1449491-86-4
p-methoxyphenyl 2,3-anhydro-6-O-(tert-butyldimethylsilyl)-α-D-allopyranoside

: 74-88-4
methyl iodide

: 1449491-90-0
p-methoxyphenyl 2,3-anhydro-6-O-(tert-butyldimethylsilyl)-4-O-methyl-α-D-allopyranoside

Guidance literature:: With silver(l) oxide; In N,N-dimethyl-formamide; at 20 ℃; for 23h; Inert atmosphere;
DOI:10.1016/j.tet.2013.07.018

Reference yield:

: 197449-36-8
p-methoxyphenyl 2,3-dideoxy-α-D-erythro-hex-2-enopyranoside

: 1449491-90-0
p-methoxyphenyl 2,3-anhydro-6-O-(tert-butyldimethylsilyl)-4-O-methyl-α-D-allopyranoside

Guidance literature:: Multi-step reaction with 3 steps

1: potassium hydrogencarbonate; dihydrogen peroxide / acetonitrile / 4 h / 20 °C

2: 1H-imidazole / dichloromethane / 4 h / 0 °C

3: silver(l) oxide / N,N-dimethyl-formamide / 23 h / 20 °C / Inert atmosphere

With 1H-imidazole; dihydrogen peroxide; potassium hydrogencarbonate; silver(l) oxide; In dichloromethane; N,N-dimethyl-formamide; acetonitrile;
DOI:10.1016/j.tet.2013.07.018

Reference yield:

: 1449491-88-6
p-methoxyphenyl 2,3-anhydro-α-D-allopyranoside

: 1449491-90-0
p-methoxyphenyl 2,3-anhydro-6-O-(tert-butyldimethylsilyl)-4-O-methyl-α-D-allopyranoside

Guidance literature:: Multi-step reaction with 2 steps

1: 1H-imidazole / dichloromethane / 4 h / 0 °C

2: silver(l) oxide / N,N-dimethyl-formamide / 23 h / 20 °C / Inert atmosphere

With 1H-imidazole; silver(l) oxide; In dichloromethane; N,N-dimethyl-formamide;
DOI:10.1016/j.tet.2013.07.018