Methyl 2-(2-methoxy-2-oxoethyl)-5-oxocyclopentene-1-carboxylate

Base Information

Chemical Name:Methyl 2-(2-methoxy-2-oxoethyl)-5-oxocyclopentene-1-carboxylate
CAS No.:58096-40-5
Molecular Formula:C₁₀H₁₂O₅
Molecular Weight:212.202
Hs Code.:
DSSTox Substance ID:DTXSID401194947

Synonyms:SCHEMBL21160122;DTXSID401194947;58096-40-5;Methyl 2-(methoxycarbonyl)-3-oxo-1-cyclopentene-1-acetate;methyl 2-(2-methoxy-2-oxoethyl)-5-oxo-1-cyclopentene-1-carboxylate;methyl 2-(2-methoxy-2-oxoethyl)-5-oxocyclopentene-1-carboxylate

Suppliers and Price of Methyl 2-(2-methoxy-2-oxoethyl)-5-oxocyclopentene-1-carboxylate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Methyl 2-(2-methoxy-2-oxoethyl)-5-oxocyclopentene-1-carboxylate

Chemical Property:

XLogP3:-0.1
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:5
Rotatable Bond Count:5
Exact Mass:212.06847348
Heavy Atom Count:15
Complexity:340

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:COC(=O)CC1=C(C(=O)CC1)C(=O)OC

Technology Process of Methyl 2-(2-methoxy-2-oxoethyl)-5-oxocyclopentene-1-carboxylate

There total 1 articles about Methyl 2-(2-methoxy-2-oxoethyl)-5-oxocyclopentene-1-carboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 74590-73-1
1,3-bis(trimethylsiloxy)-1-methoxybuta-1,3-diene

: 105-45-3
acetoacetic acid methyl ester

: 58096-40-5
methyl 2-<2-(methoxycarbonyl)-3-oxocyclopent-1-enyl>acetate

Guidance literature:: Yield given. Multistep reaction. Yields of byproduct given;

Reference yield:

: 58096-40-5
methyl 2-<2-(methoxycarbonyl)-3-oxocyclopent-1-enyl>acetate

: 1101843-02-0
methyl jasmonate

Guidance literature:: Multi-step reaction with 3 steps

1: 5%-palladium/activated carbon; hydrogen / methanol / 20 °C / 0 - 3000.3 Torr

2: caesium carbonate; tetrabutylammomium bromide / tert-butyl methyl ether / 0 - 20 °C / Inert atmosphere

3: water; lithium chloride / 120 - 130 °C

With 5%-palladium/activated carbon; tetrabutylammomium bromide; water; hydrogen; caesium carbonate; lithium chloride; In methanol; tert-butyl methyl ether;

Reference yield:

: 58096-40-5
methyl 2-<2-(methoxycarbonyl)-3-oxocyclopent-1-enyl>acetate

: 221682-41-3
(Z)-2-(2-(but-2-en-1-yl)-3-oxocyclopentyl)acetic acid

Guidance literature:: Multi-step reaction with 4 steps

1: 5%-palladium/activated carbon; hydrogen / methanol / 20 °C / 0 - 3000.3 Torr

2: caesium carbonate; tetrabutylammomium bromide / tert-butyl methyl ether / 0 - 20 °C / Inert atmosphere

3: water; lithium chloride / 120 - 130 °C

4: water; lithium hydroxide monohydrate / 20 °C

With lithium hydroxide monohydrate; 5%-palladium/activated carbon; tetrabutylammomium bromide; water; hydrogen; caesium carbonate; lithium chloride; In methanol; tert-butyl methyl ether;