BENZYLAMINE-RING-UL-14C HYDROCHLORIDE

Base Information

• Chemical Name: BENZYLAMINE-RING-UL-14C HYDROCHLORIDE
• CAS No.: 108321-65-9
• Molecular Formula: C₇H₁₀N*Cl
• Molecular Weight: 143.616
• Mol file: 108321-65-9.mol

Synonyms:Benzylamine-ring-UL-14C hydrochloride;

Chemical Property of BENZYLAMINE-RING-UL-14C HYDROCHLORIDE

Chemical Property:

• PSA: 26.02000
• LogP: 2.64760
• Storage Temp.: 2-8°C

Purity/Quality:

Safty Information:

• Hazard Codes: Xi,R
• Statements: 36/37/38
• Safety Statements: 26-36

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of BENZYLAMINE-RING-UL-14C HYDROCHLORIDE

There total 69 articles about BENZYLAMINE-RING-UL-14C HYDROCHLORIDE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

benzylamine (100-46-9) → benzylamine hydrochloride (3287-99-8,39110-74-2,108321-65-9)

Guidance literature:

With hydroxylamine hydrochloride; In ethanol; for 2h; Reflux;

DOI:10.1080/00397911.2015.1096943

Reference yield: 100.0%

benzonitrile (100-47-0) → benzylamine hydrochloride (3287-99-8,39110-74-2,108321-65-9)

Guidance literature:

With hydrogenchloride; hydrogen; In propan-1-ol; water; at 60 ℃; for 18h; under 375.038 Torr; Flow reactor;

DOI:10.1002/open.201600166

Reference yield: 99.0%

1-nitro-1-phenylmethane (622-42-4) → benzylamine hydrochloride (3287-99-8,39110-74-2,108321-65-9)

Guidance literature:

1-nitro-1-phenylmethane; With triethyl borane; potassium tert-butylate; 4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane; In tetrahydrofuran; at 100 ℃; for 24h; Inert atmosphere; Sealed tube; Green chemistry;

With hydrogenchloride; In water; at 20 ℃; for 6h; Green chemistry;

upstream raw materials:

chloroacetic acid ethyl ester

benzylamine

acetyl chloride

N,N-dibenzylhydroxylamine

Downstream raw materials:

N-benzyl-4-aminopyridine

3-benzylaminomethyl-7-chloro-chroman-4-one

5,5'-dibenzyl-1,1'-(4-oxa-heptanediyl)-bis-biguanide; dihydrochloride

N,N'-dibenzyl-benzamidine

Refernces

• 1、 Baumgarten,H.E. et al.. "-". . p. 3554 - 3561. Retrieved 1975.
• 2、 Pretorius, Anél,Ogunrombi, Modupe O.,Fourie, Hendrik,Terre'Blanche, Gisella,Castagnoli Jr., Neal,Bergh, Jacobus J.,Petzer, Jacobus P.. "Interactions of 1-methyl-3-phenylpyrrolidine and 3-methyl-1-phenyl-3-azabicyclo[3.1.0]hexane with monoamine oxidase B". . p. 4111 - 4118. Retrieved 2010.
• 3、 Das, Suman,Bhattacharjee, Jayeeta,Panda, Tarun K.. "An imidazolin-2-iminato ligand organozinc complex as a catalyst for hydroboration of organic nitriles". . p. 16812 - 16818. Retrieved 2019.
• 4、 Gao, Yuan,Walters, Grant,Qin, Ying,Chen, Bin,Min, Yimeng,Seifitokaldani, Ali,Sun, Bin,Todorovic, Petar,Saidaminov, Makhsud I.,Lough, Alan,Tongay, Sefaattin,Hoogland, Sjoerd,Sargent, Edward H.. "Electro-Optic Modulation in Hybrid Metal Halide Perovskites". . . Retrieved 2019.
• 5、 Katritzky, Alan R.,Jiang, Jinlong,Urogdi, Laszlo. "N-Triphenylphosphorylidene-1-(benzotriazol-1-yl)methylamine, a Novel Synthon Equivalent to +CH2NH2: The Preparation of Primary Amines". . p. 3303 - 3306. Retrieved 1989.
• 6、 Harinath, Adimulam,Bhattacharjee, Jayeeta,Panda, Tarun K.. "Catalytic Hydroboration of Organic Nitriles Promoted by Aluminum Complex". . p. 850 - 857. Retrieved 2019.
• 7、 Das, Shyamal,Das, Hari Sankar,Singh, Bhagat,Haridasan, Rahul Koottanil,Das, Arpan,Mandal, Swadhin K.. "Catalytic Reduction of Nitriles by Polymethylhydrosiloxane Using a Phenalenyl-Based Iron(III) Complex". . p. 11274 - 11278. Retrieved 2019.
• 8、 Darcel, Christophe,Wu, Jiajun. "Tandem Fe/Zn or Fe/In Catalysis for the Selective Synthesis of Primary and Secondary Amines?via Selective Reduction of Primary Amides". . . Retrieved 2022/03/18.
• 9、 Sarkar, Koushik,Das, Kuhali,Kundu, Abhishek,Adhikari, Debashis,Maji, Biplab. "Phosphine-Free Manganese Catalyst Enables Selective Transfer Hydrogenation of Nitriles to Primary and Secondary Amines Using Ammonia-Borane". . p. 2786 - 2794. Retrieved 2021/03/03.