allyl 2-benzylacrylate

Base Information

• Chemical Name: allyl 2-benzylacrylate
• CAS No.: 1191126-41-6
• Molecular Formula: C₁₃H₁₄O₂
• Molecular Weight: 202.253
• Mol file: 1191126-41-6.mol

Synonyms:allyl 2-benzylacrylate

Chemical Property of allyl 2-benzylacrylate

Chemical Property:

Purity/Quality:

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MSDS Files:

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Technology Process of allyl 2-benzylacrylate

There total 3 articles about allyl 2-benzylacrylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

allyl alcohol (107-18-6) + 2-benzylpropenoyl chloride (88320-94-9) → allyl 2-benzylacrylate (1191126-41-6)

Guidance literature:

With N-ethyl-N,N-diisopropylamine; In dichloromethane; at 0 - 25 ℃; Inert atmosphere;

DOI:10.1021/ol902004p

Reference yield:

benzaldehyde (100-52-7) → allyl 2-benzylacrylate (1191126-41-6)

Guidance literature:

Multi-step reaction with 2 steps

1: diethyl 2,6-dimethyl-1,4-dihydropyridine-3,5-dicarboxylate; L-proline / methanol / 2 h / 25 °C

2: 12 h / 65 °C

With diethyl 2,6-dimethyl-1,4-dihydropyridine-3,5-dicarboxylate; L-proline; In methanol; 2: |Eschenmoser Methylenation;

DOI:10.1039/c4ob00667d

Reference yield:

5-benzyl-2,2-dimethyl-1,3-dioxane-4,6-dione (3709-27-1) + eschenmoser's salt (33797-51-2) + allyl alcohol (107-18-6) → allyl 2-benzylacrylate (1191126-41-6)

Guidance literature:

at 65 ℃; for 12h;

DOI:10.1039/c4ob00667d

upstream raw materials:

allyl alcohol

2-benzylpropenoyl chloride

benzaldehyde

5-benzyl-2,2-dimethyl-1,3-dioxane-4,6-dione