[V(η6-MeC6H5)2]

Base Information

Chemical Name:[V(η6-MeC6H5)2]
CAS No.:12131-27-0
Molecular Formula:C₁₄H₁₆V
Molecular Weight:235.223
Hs Code.:

Synonyms:[V(η6-MeC6H5)2]

Suppliers and Price of [V(η6-MeC6H5)2]

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of [V(η6-MeC6H5)2]

Chemical Property:

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Technology Process of [V(η6-MeC6H5)2]

There total 1 articles about [V(η6-MeC6H5)2] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 6.0%

: 143-66-8
sodium tetraphenyl borate

: 7718-98-1
vanadium(III) chloride

: 108-88-3,15644-74-3,16713-13-6
toluene

: 12131-27-0
[V(η6-MeC6H5)2]

: 908026-09-5
[V(η6-MeC6H5)2]BPh4

Guidance literature:: With Al; AlCl₃; In toluene; (N2); suspn. of VCl3, Al and AlCl3 in toluene was refluxed overnight; filtered at room temp.; lower layer was added to aq. soln. of NaBPh4 at room temp.; filtered; washed (H2O); dried (vac., P4O10, room temp.); treated with heptane; stirred at room temp. for 2 h; filtered; washed (heptane); dried in vac. at room temp.; filtrate evapd.; elem. anal.;
DOI:10.1016/j.jorganchem.2006.04.027

Reference yield: 50.0%

: 12131-27-0
[V(η6-MeC6H5)2]

: 75-09-2
dichloromethane

: 712-74-3
1,2,4,5-tetracyanobenzene

: V(1,2,4,5-tetracyanobenzene)2*0.05CH₂Cl₂

Guidance literature:: In dichloromethane; (N2), dry box; soln. of V(C6H4(CH3)2)2 in minimal amount of CH2Cl2 addeddropwise to stirred suspn. of tetracyanobenzene (ratio 1:2), stirred fo r ca. 20 min; pptn., collected by suction filtration, dried in vac.; elem. anal.;
DOI:10.1002/anie.200600988