2-[2,4,6-tris(bis(trimethylsilyl)methyl)phenyl]-1,2,3,4-tetrahydro-2-germanaphthalene

Base Information

Chemical Name:2-[2,4,6-tris(bis(trimethylsilyl)methyl)phenyl]-1,2,3,4-tetrahydro-2-germanaphthalene
CAS No.:392335-70-5
Molecular Formula:C₃₆H₇₀GeSi₆
Molecular Weight:744.055
Hs Code.:

Synonyms:2-[2,4,6-tris(bis(trimethylsilyl)methyl)phenyl]-1,2,3,4-tetrahydro-2-germanaphthalene

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Chemical Property of 2-[2,4,6-tris(bis(trimethylsilyl)methyl)phenyl]-1,2,3,4-tetrahydro-2-germanaphthalene

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Technology Process of 2-[2,4,6-tris(bis(trimethylsilyl)methyl)phenyl]-1,2,3,4-tetrahydro-2-germanaphthalene

There total 1 articles about 2-[2,4,6-tris(bis(trimethylsilyl)methyl)phenyl]-1,2,3,4-tetrahydro-2-germanaphthalene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 33.0%

: 38256-56-3
1-(2-bromo-ethyl)-2-bromomethyl-benzene

: 135139-64-9
2,4,6-tris(bis(trimethylsilyl)methyl)phenylgermanium trichloride

: 392335-70-5
2-[2,4,6-tris(bis(trimethylsilyl)methyl)phenyl]-1,2,3,4-tetrahydro-2-germanaphthalene

Guidance literature:: With magnesium; LiAlH₄; In tetrahydrofuran; under Ar, soln. were added dropwise to dried Mg over 0.5 h, mixt. was stirred for 2 h at room temp., then LiAlH4 was added at 0°C, and suspn. was stirred for 1 h; aq. NaOH was added at 0°C, suspn. was filtered, hexane was added,solvent was evapd., residue was purified by FCC (hexane); elem. anal.;
DOI:10.1021/om020879m

Reference yield: 62.0%

: 392335-70-5
2-[2,4,6-tris(bis(trimethylsilyl)methyl)phenyl]-1,2,3,4-tetrahydro-2-germanaphthalene

: 392335-71-6
2-[2,4,6-tris(bis(trimethylsilyl)methyl)phenyl]-1,2-dihydro-2-germanaphthalene

Guidance literature:: With NBS; LiAlH₄; t-BuLi; In tetrahydrofuran; 1,2,3,4-tetrahydro-2-germanaphthalene was brominated with excess NBS (BPO cat.) in benzene under reflux followed by reduction with LiAlH4 in THFat 0°C, treatment with t-BuLi in THF at -78°C and success ive addn. aq. NH4Cl;
DOI:10.1021/om010881y

Reference yield:

: 392335-70-5
2-[2,4,6-tris(bis(trimethylsilyl)methyl)phenyl]-1,2,3,4-tetrahydro-2-germanaphthalene

: 392335-73-8
2-hydroxy-2-[2,4,6-tris(bis(trimethylsilyl)methyl)phenyl]-1,2-dihydro-2-germanaphthalene

Guidance literature:: Multi-step reaction with 4 steps

1: NBS; LiAlH₄; t-BuLi / tetrahydrofuran

2: BPO / benzene

3: LDA / tetrahydrofuran

4: not given

With NBS; LiAlH₄; t-BuLi; BPO; LDA; In tetrahydrofuran; benzene;
DOI:10.1021/om010881y