2-[2,4,6-tris(bis(trimethylsilyl)methyl)phenyl]-1,2-dihydro-2-germanaphthalene

Base Information

• Chemical Name: 2-[2,4,6-tris(bis(trimethylsilyl)methyl)phenyl]-1,2-dihydro-2-germanaphthalene
• CAS No.: 392335-71-6
• Molecular Formula: C₃₆H₆₈GeSi₆
• Molecular Weight: 742.039

Synonyms:2-[2,4,6-tris(bis(trimethylsilyl)methyl)phenyl]-1,2-dihydro-2-germanaphthalene

Chemical Property of 2-[2,4,6-tris(bis(trimethylsilyl)methyl)phenyl]-1,2-dihydro-2-germanaphthalene

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

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Technology Process of 2-[2,4,6-tris(bis(trimethylsilyl)methyl)phenyl]-1,2-dihydro-2-germanaphthalene

There total 6 articles about 2-[2,4,6-tris(bis(trimethylsilyl)methyl)phenyl]-1,2-dihydro-2-germanaphthalene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 62.0%

2-[2,4,6-tris(bis(trimethylsilyl)methyl)phenyl]-1,2,3,4-tetrahydro-2-germanaphthalene (392335-70-5) → 2-[2,4,6-tris(bis(trimethylsilyl)methyl)phenyl]-1,2-dihydro-2-germanaphthalene (392335-71-6)

Guidance literature:

With NBS; LiAlH₄; t-BuLi; In tetrahydrofuran; 1,2,3,4-tetrahydro-2-germanaphthalene was brominated with excess NBS (BPO cat.) in benzene under reflux followed by reduction with LiAlH4 in THFat 0°C, treatment with t-BuLi in THF at -78°C and success ive addn. aq. NH4Cl;

DOI:10.1021/om010881y

Reference yield:

1-(2-bromo-ethyl)-2-bromomethyl-benzene (38256-56-3) → 2-[2,4,6-tris(bis(trimethylsilyl)methyl)phenyl]-1,2-dihydro-2-germanaphthalene (392335-71-6)

Guidance literature:

Multi-step reaction with 2 steps

1: magnesium; LiAlH₄ / tetrahydrofuran

2: LiAlH₄; catalyst: benzoyl peroxide / tetrahydrofuran; benzene

With magnesium; LiAlH₄; catalyst: benzoyl peroxide; In tetrahydrofuran; benzene;

DOI:10.1021/om020879m

Reference yield:

2,4,6-tris(bis(trimethylsilyl)methyl)phenylgermanium trichloride (135139-64-9) → 2-[2,4,6-tris(bis(trimethylsilyl)methyl)phenyl]-1,2-dihydro-2-germanaphthalene (392335-71-6)

Guidance literature:

Multi-step reaction with 2 steps

1: magnesium; LiAlH₄ / tetrahydrofuran

2: LiAlH₄; catalyst: benzoyl peroxide / tetrahydrofuran; benzene

With magnesium; LiAlH₄; catalyst: benzoyl peroxide; In tetrahydrofuran; benzene;

DOI:10.1021/om020879m

upstream raw materials:

2-[2,4,6-tris(bis(trimethylsilyl)methyl)phenyl]-1,2,3,4-tetrahydro-2-germanaphthalene

N-Bromosuccinimide

1-(2-bromo-ethyl)-2-bromomethyl-benzene

2,4,6-tris(bis(trimethylsilyl)methyl)phenylgermanium trichloride

Downstream raw materials:

2-bromo-2-[2,4,6-tris(bis(trimethylsilyl)methyl)phenyl]-1,2-dihydro-2-germanaphthalene

4,10b-dihydro-4-[2,4,6-tris(bis(trimethylsilyl)methyl)phenyl][2]benzogermino[2,1-d]-1,2,3,4-trithiagermole

2-tert-butyl-2-[2,4,6-tris(bis(trimethylsilyl)methyl)phenyl]-1,2-dihydro-2-germanaphthalene

4,10b-dihydro-1-mesityl-4-[2,4,6-tris(bis(trimethylsilyl)methyl)phenyl][2]benzogermino[1,2-d][1,2,5]oxazagermole

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