bis[η5-2,5-dicyclohexyl-1-phosphacyclopentadienyl]ruthenium(II)

Base Information

Chemical Name:bis[η5-2,5-dicyclohexyl-1-phosphacyclopentadienyl]ruthenium(II)
CAS No.:448901-40-4
Molecular Formula:C₃₂H₄₈P₂Ru
Molecular Weight:595.751
Hs Code.:

Synonyms:bis[η5-2,5-dicyclohexyl-1-phosphacyclopentadienyl]ruthenium(II)

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of bis[η5-2,5-dicyclohexyl-1-phosphacyclopentadienyl]ruthenium(II)

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Technology Process of bis[η5-2,5-dicyclohexyl-1-phosphacyclopentadienyl]ruthenium(II)

There total 1 articles about bis[η5-2,5-dicyclohexyl-1-phosphacyclopentadienyl]ruthenium(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 71.0%

: dichloro(1,5-cyclooctadiene)ruthenium(II)

: 448901-38-0
1-phenyl-2,5-dicyclohexylphosphole

: 448901-40-4
bis[η5-2,5-dicyclohexyl-1-phosphacyclopentadienyl]ruthenium(II)

Guidance literature:: With lithium; AlCl₃; In tetrahydrofuran; THF soln. phospholide was treated with Li and stirred at room temp., react. mixt. was filtered, AlCl3 was added to filtrate at 0°C and allowed to warm to room temp., (RuCl2(cod))n in THF was added and refluxedfor 48 h; react. mixt. was cooled, volatiles were removed under reduced pressure, residue was extd. with hexane, product was purified by preparative TLC on silica (hexane) under Ar atm., rectystn. from hot hexane; elem. anal.;
DOI:10.1021/om020189i

Reference yield: 46.0%

: 448901-40-4
bis[η5-2,5-dicyclohexyl-1-phosphacyclopentadienyl]ruthenium(II)

: 75-36-5
acetyl chloride

: 1004314-74-2
(PC₄H₂(C₆H₁₁)2)Ru(CH₂CP(O)C₄H₂(C₆H₁₁)2)

: 1004314-79-7
(PC₄H₂(C₆H₁₁)2)Ru(PC₄H(C₆H₁₁)2COCH₃)

Guidance literature:: With AlCl₃; In dichloromethane; Ru complex reacted with MeCOCl and AlCl3 in refluxing CH2Cl2 for 24 h; purified by column chromy. (silica gel);
DOI:10.1021/om701063k

Reference yield: 29.0%

: 448901-40-4
bis[η5-2,5-dicyclohexyl-1-phosphacyclopentadienyl]ruthenium(II)

: 79-03-8
propionyl chloride

: 1004315-07-4
(PC₄H₂(C₆H₁₁)2)Ru(CH(CH₃)CP(O)C₄H₂(C₆H₁₁)2)

: 1004315-07-4
(PC₄H₂(C₆H₁₁)2)Ru(CH(CH₃)CP(O)C₄H₂(C₆H₁₁)2)

: 1004315-09-6
(PC₄H₂(C₆H₁₁)2)Ru(PC₄H(C₆H₁₁)2COC₂H₅)

Guidance literature:: With AlCl₃; In dichloromethane; Ru complex reacted with EtCOCl and AlCl3 in refluxing CH2Cl2 for 24 h; detd. by (1)H and (31)P NMR spectra; mixt. of E and Z isomers (>97/<3) of Fe-alkenylidene complex obtained, total yield 13%;
DOI:10.1021/om701063k