Methyl 2-fluorosulfonylbenzoate

Base Information

Chemical Name:Methyl 2-fluorosulfonylbenzoate
CAS No.:137654-46-7
Molecular Formula:C₈H₇FO₄S
Molecular Weight:218.206
Hs Code.:
European Community (EC) Number:832-914-8

Synonyms:Methyl 2-(fluorosulfonyl)benzoate;137654-46-7;Methyl 2-fluorosulfonylbenzoate;2-(Fluorosulfonyl)-methyl ester benzoic acid;Methyl2-(fluorosulfonyl)benzoate;AKOS037478275;fluorosulfonylbenzoic acid methyl ester;VS-0040;EN300-225039;F74986;Z2216561476

Suppliers and Price of Methyl 2-fluorosulfonylbenzoate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 3 raw suppliers

Chemical Property of Methyl 2-fluorosulfonylbenzoate

Chemical Property:

XLogP3:1.5
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:5
Rotatable Bond Count:3
Exact Mass:218.00490804
Heavy Atom Count:14
Complexity:306

Purity/Quality:: 95% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:COC(=O)C1=CC=CC=C1S(=O)(=O)F

Technology Process of Methyl 2-fluorosulfonylbenzoate

There total 4 articles about Methyl 2-fluorosulfonylbenzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

: 4892-02-8
Methyl thiosalicylate

: 137654-46-7
methyl 2-(fluorosulfonyl)benzoate

Guidance literature:: With pyridine; hydrogenchloride; potassium fluoride; water; In acetonitrile; at 20 ℃; for 20h; Electrochemical reaction; Green chemistry;
DOI:10.1021/jacs.9b06126

Reference yield:

: 26638-43-7
2-methoxycarbonylbenzenesulfonyl chloride

: 137654-46-7
methyl 2-(fluorosulfonyl)benzoate

Guidance literature:: With potassium hydrogen difluoride; In water; acetonitrile; at 20 ℃;
DOI:10.1073/pnas.1909972116

Reference yield:

: 134-20-3
2-carbomethoxyaniline

: 137654-46-7
methyl 2-(fluorosulfonyl)benzoate

Guidance literature:: 2-carbomethoxyaniline; With tetrafluoroboric acid; tert.-butylnitrite; In ethanol; water; at 0 - 20 ℃; for 1h;

With 6,6'-dimethyl-2,2'-bipyridine; potassium hydrogen difluoride; 1,4-diazabicyclo [2.2.2] octane-1,4-diium-1,4-disulfinate; copper dichloride; In acetonitrile; at 20 ℃; for 12h; Sealed tube; Inert atmosphere;
DOI:10.1021/acs.orglett.0c00484